Journal ArticleDOI
Surprisingly efficient intramolecular addition of carbon radicals to carbonyl groups: a ready route to cycloalkanols
Ray Tsang,Bert Fraser-Reid +1 more
Reads0
Chats0
About:
This article is published in Journal of the American Chemical Society.The article was published on 1986-12-01. It has received 53 citations till now. The article focuses on the topics: Acetal & Free-radical reaction.read more
Citations
More filters
Journal ArticleDOI
Distonic radical cations in gaseous and condensed phase
TL;DR: In this paper, the authors demontre que les radicaux cationiques CH 3 OH +, CH 3 NH 2 + and CH 3 ClH + ont des isomeres stables.
Journal ArticleDOI
Radical-Mediated 1,2-Formyl/Carbonyl Functionalization of Alkenes and Application to the Construction of Medium-Sized Rings
TL;DR: A novel radical 1, 2-formylfunctionalization of alkenes involving 1,2(4,5)-formyl migration triggered by addition of various carbon- and heteroatom-centered radicals has been developed for the first time, thus providing straightforward access to diverse β-functionalized aldehydes with good efficiency, remarkable selectivity, and excellent functional group tolerance.
Journal ArticleDOI
Some Progeny of 2,3-Unsaturated SugarsThey Little Resemble Grandfather Glucose: Twenty Years Later,1
Journal ArticleDOI
Radicals from Epoxides. Intramolecular Addition to Aldehyde and Ketone Carbonyls
Alfonso Fernández-Mateos,E. M. Martin de la Nava,G. Pascual Coca,and A. Ramos Silvo,R. Rubio Gonzalez +4 more
TL;DR: The behavior of epoxy alcohols with titanocene chloride to afford saturated diols and epoxy esters that give unsaturated hydroxy esters are discussed in this paper.
Journal ArticleDOI
Developments in cyclisation reactions
TL;DR: Cyclisations cationiques, radicalaires and anioniques as discussed by the authors are catalysees par des metaux, and they can be classified into three classes: cationique, radicalaine and radicalaine.