Journal ArticleDOI
Sustainable Metal Catalysis with Iron: From Rust to a Rising Star?
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This article is published in Angewandte Chemie.The article was published on 2008-04-21. It has received 1041 citations till now. The article focuses on the topics: Rust.read more
Citations
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Direct C-H transformation via iron catalysis.
Journal ArticleDOI
Zr-based metal-organic frameworks: design, synthesis, structure, and applications.
TL;DR: Advances in Zr-MOFs since 2008 are summarized and reviewed from three aspects: design and synthesis, structure, and applications to provide guidance for the in-depth investigation of MOFs towards practical applications.
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3d Transition Metals for C-H Activation.
Parthasarathy Gandeepan,Thomas Müller,Daniel Zell,Gianpiero Cera,Svenja Warratz,Lutz Ackermann +5 more
TL;DR: A comprehensive overview on first row transition metal catalysts for C-H activation until summer 2018 is provided.
References
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Iron-Catalyzed Reactions in Organic Synthesis
TL;DR: A new iron(III) halide-promoted aza-Prins cyclization between γ,δ-unsaturated tosylamines and aldehydes provides six-membered azacycles in good to excellent yields.
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A Predictably Selective Aliphatic C-H Oxidation Reaction for Complex Molecule Synthesis
Mark S. Chen,M. Christina White +1 more
TL;DR: An iron (Fe)–based small molecule catalyst that uses hydrogen peroxide (H2O2) to oxidize a broad range of substrates and Predictable selectivity is achieved solely on the basis of the electronic and steric properties of the C–H bonds, without the need for directing groups.
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Preparation and molecular and electronic structures of iron(0) dinitrogen and silane complexes and their application to catalytic hydrogenation and hydrosilation.
TL;DR: Structural characterization of a high spin iron(0) alkyne and a bis(silane) sigma-complex has been accomplished and in combination with isotopic labeling studies provides insight into the mechanism of both catalytic C-H and catalyticC-Si bond formation.
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An efficient and chemoselective iron catalyst for the hydrogenation of ketones.
Charles P. Casey,Hairong Guan +1 more
TL;DR: Mechanistic studies have established a reversible hydrogen transfer step followed by rapid dihydrogen activation and the same iron complex also catalyzes transfer hydrogenation of ketones.