Synthesis and characterization of complexes containing the bis(1, 2-diolato)-oxotechnetium(V) core
TL;DR: In this article, the properties of TcOCl 4 O (4-x ) and Na[TcO(OCH 2 CH 2 O) 2 ] (2 ) have been determined by standard methods and refined to R 1 = 0.0694, R 2 =0.0613, on the basis of 2887 independent reflections.
About: This article is published in Inorganica Chimica Acta.The article was published on 1987-04-22. It has received 35 citations till now. The article focuses on the topics: Square pyramidal molecular geometry & Inorganic compound.
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296 citations
TL;DR: In this article, the main structural features of 240 Tc complexes whose X-ray crystal structure has been determined during the period 1986-1992 were reported, with 294 references and 41 figures.
140 citations
TL;DR: In this paper, the electrochemical and structural aspects of homoleptic quinoidal (or pseudo-quinoidal) molecules coordinated to (single) transition metal ions are updated. But, since 1,2-dioxolenes are redox-active molecules able to shuttle reversibly through the sequence quinone/hydroquinone/catechol, their metal complexes can display both the ligand-and the metal-centred electron transfers, which in some cases can overlap or trigger internal charge reorganizations.
104 citations
TL;DR: In this article, the coordination chemistry of technetium and rhenium is reviewed and the complexes are arranged according to the donor-atom sets in the coordination sphere, where the donor atoms are chosen according to their positions in the atom sets.
Abstract: This review covers the coordination chemistry of technetium(V) and — to some extent — rhenium(V). In this survey, the complexes are arranged according to donor-atom sets in the coordination sphere.
49 citations
TL;DR: The chemistry behind the development of technetium-99m (Tc- 99m) complexes useful for determining renal (kidney) function is discussed and the design of these compounds so that they will be stable in vivo, actively taken up by the kidney, excreted from the body without being metabolized.
47 citations
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TL;DR: In this article, the isolation and chemistry of technetium and promethium and some of their compounds are described and discussed. But they do not discuss the properties of these compounds.
Abstract: Examines the isolation and chemistry of technetium and promethium and some of their compounds.
95 citations