Journal ArticleDOI
Synthesis and Diels-Alder reactions of 1,3-dimethyl-4-(phenylsulfonyl)-4H-furo[3,4-b]indole. A new annulation strategy for the construction of ellipticine and isoellipticine
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This article is published in Journal of Organic Chemistry.The article was published on 1984-11-01. It has received 118 citations till now. The article focuses on the topics: Annulation & Diels–Alder reaction.read more
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Isolation and synthesis of biologically active carbazole alkaloids
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A Comprehensive History of Arynes in Natural Product Total Synthesis
TL;DR: All reports of total syntheses that utilize arynes in ways that build complexity or introduce motifs essential to the completion of their targets are recounted.
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Sodium borohydride in carboxylic acid media: a phenomenal reduction system
TL;DR: In this article, the union of sodium borohydride and carboxylic acids has yielded an amazingly versatile and efficient set of reducing reagents, including acyloxyborohydride species.
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Pyridynes and indolynes as building blocks for functionalized heterocycles and natural products
TL;DR: This review provides a brief historical perspective on the field of hetarynes, in addition to a discussion of pyridyne and indolyne methodologies, and highlights the use of p Pyridynes, indolynes, and related strained intermediates in natural product synthesis.
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Hydrogen Atom Abstraction by Permanganate: Oxidations of Arylalkanes in Organic Solvents.
TL;DR: Rates of H(*) abstraction by (n)()Bu( 4)NMnO(4) correlate with rates of abstraction by oxygen radicals, which are explained on the basis of its ability to form an 80 +/- 3 kcal/mol bond to H(*).
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The biogenetic, synthetic and biochemical aspects of ellipticine, an antitumor alkaloid
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