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Journal ArticleDOI

Synthesis and structure of the isomorphous bromo- and chlorodiethyldithiocarbamatotellurium(II), Te{(C2H5)2NCS2}X (XBr, Cl)

01 Jun 1996-Polyhedron (Pergamon)-Vol. 15, Iss: 18, pp 3123-3128
TL;DR: Bromo and chloro-susbtituted tellurium(II) dithiocarbamate complexes were prepared by the reaction of iododiethyldithium-carbamatotellurium (II), dissolved in dichloro-methane, with a suspension of their respective silver halide as mentioned in this paper.
About: This article is published in Polyhedron.The article was published on 1996-06-01. It has received 4 citations till now. The article focuses on the topics: Dithiocarbamate.
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Journal ArticleDOI
TL;DR: In this article, a survey of the literature of tellurium(II)/(IV) 1,1-dithiolates (dithiocarbamate, xanthate, dithiophosphate, or dithIophosphinate) is presented.

44 citations

Journal ArticleDOI
TL;DR: The first Te-C cleaved product was obtained in the reaction of C4H8TeI2 (1,2,3,4,5,6-hexahydro-1,1-diiodotellurophene) with NH4S2CNHC6H5 (ammonium aniline dithiocarbamate) as mentioned in this paper.

12 citations

Journal ArticleDOI
TL;DR: The ternary complexes [Pd(RaaiX)(SS)ClO4] as discussed by the authors, where RaaiX is a N(1)-alkyl-2-(arylazo)imidazole (p-RC6H4N =NC3H2NN(1) X; X = Me, or Et, and R = H, Me or Cl) and SS = N,N-diethyldithiocarbamate or morpholinedithiamato (II) in solution.
Abstract: The ternary complexes [Pd(RaaiX)(SS)ClO4) where RaaiX is a N(1)-alkyl-2-(arylazo)imidazole (p-RC6H4N =NC3H2NN(1) X; X = Me, or Et, and R = H, Me or Cl) and SS = N,N-diethyldithiocarbamate or morpholinedithiocarbamate have been prepared and characterized by elemental analysis, i.r., u.v.-vis. and 1H-n.m.r. data. Electrochemical studies show azo reduction. The complexes are thermally unstable and decompose to bis(dithiocarbamato)palladium(II) in solution.

11 citations

Journal ArticleDOI
TL;DR: A comprehensive review of the structural chemistry of tellurium can be found in this paper, which covers the field through most of the 1990s, through to the early 1990s.
Abstract: Since the author's last surveys of this field in 1983 and 1987,1,2 there has been considerable developments in the structural chemistry of tellurium. A comprehensive review covers the field through most of 1993.3

8 citations