Journal ArticleDOI
Synthesis, crystal and molecular structure of calcium oxo ethoxide, [Ca6(µ4-O)2(µ3-OEt)4(OEt)4]·14EtOH
Nataliya Ya. Turova,E. P. Turevskaya,Vadim G. Kessler,Alexander I. Yanovsky,Yuri T. Struchkov +4 more
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TLDR
The hexanuclear complex of calcium oxo ethoxide ethanol solvate, [Ca6O2(OEt)8]·14EtOH 1 has been isolated after the prolonged refluxing of an ethanol solution of calcium ethoxide in the presence of the oxygen in air and studied by X-ray diffraction as mentioned in this paper.Abstract:
The hexanuclear complex of calcium oxo ethoxide ethanol solvate, [Ca6O2(OEt)8]·14EtOH 1 has been isolated after the prolonged refluxing of an ethanol solution of calcium ethoxide in the presence of the oxygen in air and studied by X-ray diffraction; the metal-oxygen framework is built of two [Ca4O4] cubes sharing a common [Ca2O2] face, which involves both oxo groups.read more
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Stable "inverse" sandwich complex with unprecedented organocalcium(I): crystal structures of [(thf)(2)Mg(Br)-C(6)H(2)-2,4,6-Ph(3)] and [(thf)(3)Ca{mu-C(6)H(3)-1,3,5-Ph(3)}Ca(thf)(3)].
TL;DR: Quantum chemical calculations shed light on the bonding situation in this very unusual dinuclear Ca(I) compound.
Journal ArticleDOI
Novel heterometallic alkoxide coordination systems of polyols (glycols, di- and tri-ethanolamines) derived from the corresponding homometallic moieties
Anirudh Singh,Ram C. Mehrotra +1 more
TL;DR: In this article, the synthesis and characterization of these novel heterometallic coordination systems with polyols (glycols, di- and tri-ethanolamines (teaH 3 )), derived from the corresponding homometallic species, have been reviewed with a full list of compounds described till 2002.
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Volatile metallo-organic precursors for depositing inorganic electronic materials
TL;DR: In this paper, the authors present a method of photolytic decomposition of metallo-organic molecular precursors for chemical vapour deposition (MOCVD) under UHV conditions.
References
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The infra-red spectra of complex molecules
TL;DR: In this article, the authors present a survey of research work in physics, physical sciences, and physical chemistry, focusing on physics, chemistry, physics, and biology. But they do not discuss their work in this paper.
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A very large calcium dialkoxide molecular aggregate having a CdI2 core geometry: Ca9(OCH2CH2OMe)18(HOCH2CH2OMe)2
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Molybdenum and tungsten (VI) bimetallic alkoxides. Decomposition accompanied by dialkylether elimination
TL;DR: In this paper, the existence of (1:1) bimetallic complexes in alcohol solutions has been proved by conductometric titration curves of MO(OR)4, and MO2 (OR)2 (M = Mo, W; R = Et, iPr, C2H4OMe) by sodium (or lithium) alkoxides.