Journal ArticleDOI
Synthesis of (1,2-benzenediolato(2-)-0,0')oxobis(1-piperidinolato(1-)-0,n)molybdenum( vi), [moo(c5h10no)2(c6h4o2)], and structure determination by correlated h-1-c-13 two-dimensional nmr-spectroscopy and x-ray crystallography
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This article is published in Inorganic Chemistry.The article was published on 1985-01-01. It has received 19 citations till now. The article focuses on the topics: Nuclear magnetic resonance spectroscopy & X-ray crystallography.read more
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Book ChapterDOI
The Chemistry of Transition Metal Complexes Containing Catechol and Semiquinone Ligands
Journal ArticleDOI
Reactivity of Mo−Ot Terminal Bonds toward Substrates Having Simultaneous Proton- and Electron-Donor Properties: A Rudimentary Functional Model for Oxotransferase Molybdenum Enzymes§
TL;DR: In order to study the reactivity pattern of Mo−Ot bonds associated with anionic sulfur ligands, precursor complexes MoO2L·D (H2L = S-methyl 3-(2-hydroxyphenyl)methylenedithiocarbazate; D = CH3OH (1), H2O (2)) were synthesized as discussed by the authors.
Journal ArticleDOI
Pinacol as a New Green Reducing Agent: Molybdenum‐ Catalyzed Chemoselective Reduction of Sulfoxides and Nitroaromatics
Nuria García,Patricia García-García,Manuel A. Fernández-Rodríguez,Ruben Rubio,María R. Pedrosa,Francisco J. Arnáiz,Roberto Sanz +6 more
TL;DR: In this paper, the authors thank MICINN for "Juan de la Cierva" and "Ramon y Cajal" contracts and the Junta de Castilla y Leon (BU021 A09 and GR-172) for financial support.
Journal ArticleDOI
Molybdenum and Tungsten Oxidoreductase Models
TL;DR: In this paper, a micro-review gives an overview about advances in bioinorganic model chemistry for molybdenum-and tungsten-dependent oxidoreductases with respect to specific aspects of the evolution, structure or function of distinct active-site properties.
Journal ArticleDOI
Synthesis, spectral and electrochemical studies of arylazopyridine complexes of palladium(ii) with dioxolenes
TL;DR: The position of the LLCT band is largely dependent on the substituent type on the catechol frame and is qualitatively assigned as the 3b 1 (cat) → π*(aap) transition as mentioned in this paper.