Journal ArticleDOI
Synthesis of Structurally Controlled, Highly Branched Polymethacrylates) by Radical Polymerization Through the Design of a Monomer Having Hierarchical Reactivity
Yangtian Lu,Shigeru Yamago +1 more
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In this article, the controlled synthesis of highly branched (HB) poly(methyl methacrylate) (PMMA) with a molecular weight of up to 88 × 103 g mol and low dispersity was achieved by the radical copolymeri...Abstract:
The controlled synthesis of highly branched (HB) poly(methyl methacrylate) (PMMA) with a molecular weight of up to 88 × 103 g mol and low dispersity (Đ < 2.0) was achieved by the radical copolymeri...read more
Citations
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Journal ArticleDOI
Photoorganocatalyzed Divergent Reversible-Deactivation Radical Polymerization towards Linear and Branched Fluoropolymers
TL;DR: This work developed a photoorganocatalyzed divergent synthetic approach based on reversible deactivation radical polymerization (RDRP) that enables the preparation of both linear and branched fluoropolymers of low Ð, tunable degree of branching and high chain-end fidelity by exposing to LED light irradiation under metal-free conditions.
Journal ArticleDOI
Expanding the toolbox of controlled/living branching radical polymerization through simulation-informed reaction design
TL;DR: In this paper , a controlled/living branching polymerization was achieved by copolymerizing α-haloacrylate with conventional vinyl monomers via atom transfer radical polymerization.
Journal ArticleDOI
Visible-Light-Mediated Controlled Radical Branching Polymerization in Water.
Kriti Kapil,Grzegorz Szczepaniak,Michael R. Martinez,Hironobu Murata,Arman Moini Jazani,Jae Hui Jeong,Subha R. Das,Krzysztof Matyjaszewski +7 more
TL;DR: In this paper , a branched polymethacrylates were synthesized by green-light-induced atom transfer radical polymerization (ATRP) under biologically relevant conditions in the open air.
Journal ArticleDOI
Chain-growth Click Copolymerization for Synthesis of Branched Copolymers with Tunable Branching Density
TL;DR: In this article , a facile synthesis of (hyper)branched copolymers with tunable degree of branching via one-pot chain-growth copper-catalyzed azide-alkyne cycloaddition (CuAAC) reactions was reported.
Journal ArticleDOI
Practical synthesis of dendritic hyperbranched polymers by reversible deactivation radical polymerization
TL;DR: In this article, a new molecular design for the monomer inducing the branching structure, in which the reactivity of the dormant group changes from inactive to active upon the reaction and incorporation of the polymer backbone, was described.
References
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Book
Comprehensive handbook of chemical bond energies
TL;DR: In this article, experimental methods for measuring BDEs are presented for measuring C-H bonds, C-C bonds, and C -C-C-H-C Bonds.
Journal ArticleDOI
About Dendrimers: Structure, Physical Properties, and Applications
Journal ArticleDOI
Designing dendrimers for biological applications.
TL;DR: Advances in understanding of the role of molecular weight and architecture on the in vivo behavior of dendrimers, together with recent progress in the design of biodegradable chemistries, has enabled the application of these branched polymers as anti-viral drugs, tissue repair scaffolds, targeted carriers of chemotherapeutics and optical oxygen sensors.
Journal ArticleDOI
Hyperbranched polymers: from synthesis to applications
TL;DR: In this article, a couple-monomer methodology (CMM) is proposed for hyperbranched polymers, which is based on the in situ formation of ABn intermediates from specific monomer pairs.
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