Synthesis of Wieland-Miescher Ketone Analogues-Potential Substrates for the Carbocyclic Frameworks
TL;DR: In this paper, the synthesis of 3,4,8,8a-tetrahydro-8a(2-bromo-1-cyclo-alkenylmethyl)-1,6(2H,7H)-naphthalene-diones is reported.
About: This article is published in Synthetic Communications.The article was published on 2006-09-23. It has received 3 citations till now. The article focuses on the topics: Wieland–Miescher ketone.
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TL;DR: In this paper, the authors presented a study that was supported by the Ministerio de Ciencia e Innovació (Spain)-FEDER through projects CTQ2007-67661338/BQU, CTQ 2007-62771 /BQU and Consolider Ingenio 2010 CSD2007-00006.
Abstract: This research was supported by the Ministerio de Ciencia e Innovacion (Spain)-FEDER through projects CTQ2007-
61338/BQU, CTQ2007-62771/BQU and Consolider Ingenio 2010 CSD2007-00006. Thanks are also due to the Comissionat per a Universitats i Recerca (Catalonia) for Grant 2005SGR-00442, Generalitat Valenciana for Grant (GVPRE/
2008/006) and the University of Alicante (GRJ06-05).
55 citations
TL;DR: A general and efficient route to 2-substituted 1,3-cyclopentadiones 3 has been developed and is amenable to multigram scale preparations of these useful synthetic intermediates.
Abstract: A general and efficient route to 2-substituted 1,3-cyclopentadiones 3 has been developed. This operationally simple, two-step procedure is amenable to multigram scale preparations of these useful synthetic intermediates. These compounds are then transformed to previously unknown, higher analogues of the Hajos-Parrish-Eder-Sauer-Wiechert ketone (enone 1, R = Me) following an enantioselective Robinson annulation.
16 citations
TL;DR: In this article, the synthesis of 3,4,8,8a-tetrahydro-8a(2-bromo-1-cyclo-alkenylmethyl)-1,6(2H,7H)-naphthalene-diones is reported.
Abstract: The synthesis of the hitherto unknown 3,4,8,8a-tetrahydro-8a(2-bromo-1-cyclo-alkenylmethyl)-1,6(2H,7H)-naphthalene-diones are reported.
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