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Temperature-independent transport in high-mobility pentacene transistors

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TLDR
In this article, the authors explored the charge-carrier transport mechanism in the organic semiconductor pentacene using thin-film transistor structures and found that the variation of the field-effect mobility with temperature differs from sample to sample, ranging from thermally activated to temperature-independent behavior.
Abstract
The charge-carrier transport mechanism in the organic semiconductor pentacene is explored using thin-film transistor structures. The variation of the field-effect mobility with temperature differs from sample to sample, ranging from thermally activated to temperature-independent behavior. This result excludes thermally activated hopping as the fundamental transport mechanism in pentacene thin films, and suggests that traps and/or contact effects may strongly influence the observed characteristics. These results also indicate that field-effect transistors may not be appropriate vehicles for illuminating basic transport mechanisms in organic materials.

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Journal ArticleDOI

Organic Thin Film Transistors for Large Area Electronics

TL;DR: In this article, the authors present new insight into conduction mechanisms and performance characteristics, as well as opportunities for modeling properties of organic thin-film transistors (OTFTs) and discuss progress in the growing field of n-type OTFTs.
Journal ArticleDOI

Integrated Optoelectronic Devices Based on Conjugated Polymers

TL;DR: An all-polymer semiconductor integrated device is demonstrated with a high-mobility conjugated polymer field-effect transistor driving a polymer light-emitting diode (LED) of similar size, which represents a step toward all- polymer optoelectronic integrated circuits such as active-matrix polymer LED displays.
Journal ArticleDOI

Organic-inorganic hybrid materials as semiconducting channels in thin-film field-effect transistors

TL;DR: A thin-film field-effect transistor having an organic-inorganic hybrid material as the semiconducting channel was demonstrated and molecular engineering of the organic and inorganic components of the hybrids is expected to further improve device performance for low-cost thin- film transistors.
Journal ArticleDOI

The larger acenes: versatile organic semiconductors.

TL;DR: New approaches to add functionality were developed to improve the processability of these materials in solution, allowing the synthesis of acenes larger than pentacene, which have hitherto been largely unavailable and poorly studied.
References
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Journal ArticleDOI

Studies of polaron motion: Part I. The molecular-crystal model

TL;DR: In this paper, a model for polaron motion is described, in simplified form, incorporating the principal physical features of the problem, and the conditions under which the size of the polaron becomes comparable to a lattice spacing (small) are discussed.
Journal ArticleDOI

Pentacene-based organic thin-film transistors

TL;DR: In this paper, the authors show that the large sub-threshold slope typically observed is not an intrinsic property of the organic semiconducting material and that devices with sub-reshold slope similar to amorphous silicon devices are possible.
Journal ArticleDOI

Ultrapure, High Mobility Organic Photoconductors*

TL;DR: In this article, the authors demonstrate that high charge carrier mobility is an inherent property of organic molecular crystals at low temperatures and demonstrate that charge carrier transport measurements are a sensitive tool for the analytical characterization of high purity organic molecular crystal.
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