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Template strategies with MOFs
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TLDR
In this paper, a review of template strategies for the synthesis of metal-organic frameworks (MOFs) is presented, with an overview of the morphology effect in MOFs application as well as applying them as precursors and templates for directed synthesis of diverse nano-materials.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2019-05-15. It has received 222 citations till now.read more
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Recent progress in metal-organic frameworks as active materials for supercapacitors
TL;DR: In this article, the recent progress in various branches of MOFs materials including porous coordination networks, two-dimensional (2D) MOF, entangled MOFs, polyoxometalate MOFs (POMOFs), heterometallic MOFs and some new emerging MOF types were systematically introduced and summarized.
Controlling ZIF-8 nano and microcrystal formation and reactivity through zinc salts variations
TL;DR: In this paper, the reactivity of the Zn(+2) salt in the growth solution can also markedly affect the size and the morphology of ZIF-8 particles Small Zif-8 nanocrystals with diameters varying between ca 50 and 200 nm were obtained with reactive zinc salts.
Journal ArticleDOI
Controlling the morphology of metal–organic frameworks and porous carbon materials: metal oxides as primary architecture-directing agents
Jongkook Hwang,Aleksander Ejsmont,Ralph Freund,Joanna Goscianska,Bernhard V. K. J. Schmidt,Stefan Wuttke,Stefan Wuttke +6 more
TL;DR: It is predicted that major research advances in morphology control of metal-organic frameworks and porous carbons will facilitate the use of these materials in addressing major needs of the society, especially the grand challenges of energy, health, and environment.
Journal ArticleDOI
Heterogeneous Interface Induced the Formation of Hierarchically Hollow Carbon Microcubes against Electromagnetic Pollution.
Honghong Zhao,Xianzhu Xu,Yahui Wang,Dingge Fan,Dawei Liu,Kaifeng Lin,Ping Xu,Xijiang Han,Yunchen Du +8 more
TL;DR: It is found that the SiO2 layer can effectively counteract the inward shrinkage of organic frameworks during high-temperature pyrolysis due to intensive interfacial interaction.
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Reuse of Predesigned Dual-Functional Metal Organic Frameworks (DF-MOFs) after Heavy Metal Removal
TL;DR: The systematic design of dual-functionalized metal organic framework (TMU-81) is reported by incorporating sulfonyl and amide groups for the removal of Cd(II), Cu( II) and Cr(II) ions from simulated aqueous solutions suggesting that the strong host - guest interactions between cations and the donor sites play a major role in adsorption process.
References
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Journal ArticleDOI
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Mohamed Eddaoudi,Jaheon Kim,Nathaniel L. Rosi,David T. Vodak,Joseph Wachter,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Metal-organic framework (MOF-5), a prototype of a new class of porous materials and one that is constructed from octahedral Zn-O-C clusters and benzene links, was used to demonstrate that its three-dimensional porous system can be functionalized with the organic groups and can be expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.
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Large Area, Few-Layer Graphene Films on Arbitrary Substrates by Chemical Vapor Deposition
Alfonso Reina,Xiaoting Jia,John T. Ho,Daniel Nezich,Hyungbin Son,Vladimir Bulovic,Mildred S. Dresselhaus,Jing Kong +7 more
TL;DR: The transparency, conductivity, and ambipolar transfer characteristics of the films suggest their potential as another materials candidate for electronics and opto-electronic applications.
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Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
Kyo Sung Park,Zheng Ni,Adrien P. Côté,Jae Yong Choi,Rudan Huang,Fernando J. Uribe-Romo,Hee K. Chae,Michael O'Keeffe,Omar M. Yaghi +8 more
TL;DR: Study of the gas adsorption and thermal and chemical stability of two prototypical members, ZIF-8 and -11, demonstrated their permanent porosity, high thermal stability, and remarkable chemical resistance to boiling alkaline water and organic solvents.
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A chromium terephthalate-based solid with unusually large pore volumes and surface area.
Gérard Férey,Gérard Férey,Caroline Mellot-Draznieks,Christian Serre,Franck Millange,Julien Dutour,Suzy Surblé,Irene Margiolaki +7 more
TL;DR: This crystal structure for porous chromium terephthalate, MIL-101, with large poresizes and surface area has potential as a nanomold for monodisperse nanomaterials, as illustrated here by the incorporation of Keggin polyanions within the cages.