Journal ArticleDOI
TGA, DTA and DSC studies of phosphiniminocyclotrithiazenes, R3P=NS3N3 [R=(i) C6H5-, (ii) C5H10N-, (iii) OC4H8N-, (iv) H3CNC4H8N-]
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In this paper, the thermal decomposition behavior of phosphiniminocyclotrithiazenes has been studied for the first time by employing thermogravimetric (TG), differential thermal (DT), and differential scanning calorimetric methods.About:
This article is published in Thermochimica Acta.The article was published on 1997-08-25. It has received 5 citations till now. The article focuses on the topics: Thermal decomposition & Thermogravimetric analysis.read more
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Aminophosphines: their chemistry and role as ligands and synthons
TL;DR: The chemistry of simple acyclic aminophosphines (synthesis, characterization, reactivity and applications) is covered and particular focus is given to their ability to form chalcogenides along with their role played as ligands in coordination chemistry and as synthons in inorganic heterocyclic chemistry as mentioned in this paper.
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Studies on electrochemical and coordination behaviour of phosphiniminocyclotrithiazenes
U. Swarnalatha,Akella Sivaramakrishna,C S Venkatachalam,M. N. Sudheendra Rao,Tomonori Inoue,Tadaharu Ueda,Masashi Hojo +6 more
TL;DR: In this paper, the coordination behavior of several symmetrically and unsymmetrically substituted phosphiniminocyclotrithiazenes have been studied and shown to have different reduction potentials.
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Studies on Iodination Reactions of Phosphiniminocyclotrithiazenes
TL;DR: Iodination reactions of various phosphiniminocyclotrithiazenes [R3PNS3N3; R = (i) phenyl-, (ii) morpholino-, and (iii) p-chlorophenyl-] have been studied under different experimental conditions.
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Halogenation Reactions of Phosphiniminocyclotrithiazenes: Search for New Inorganic Heterocycles
TL;DR: In this article, the chemistry of tetrasulfur tetranitride is studied and the reaction of symmetrically substituted R3PN-S3N3 [R = Ph, OC4H8N,...
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Electron Impact Mass Spectral Fragmentation Patterns of Two Six-membered Phosphiniminocyclothiazenes, (PH)[(C6H11)2N](R2N)PN-S3N3—A Comparison
TL;DR: In this article, the stability aspects from the mass spectral fragmentation patterns of two phosphiniminocyclotrithiazenes of the type (C6H5)[(C 6H11)2N](R2N)P˭N−S3N3 [R‒Me (1) and n-Bu (2)].
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Cyclic SN compounds and phosphorus reagents—VII. Reactions of S4N4 with tertiary (amino)phosphines: Synthesis and characterization of (R2N)3PN-S3N3 derivatives and their addition products with norbornadiene. X-ray crystal structure of (C5H10N)3PN-S3N3
TL;DR: The single crystal X-ray structure of (C5H10N)3PN-S3N3 (triclinic system, space group P1) gave the unit cell dimensions as discussed by the authors.