The Chemistry and Applications of Metal-Organic Frameworks
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"The Chemistry and Applications of M..." refers background in this paper
...These materials are constructed by joining metal-containing units [secondary building units (SBUs)] with organic linkers, using strong bonds (reticular synthesis) to create open crystalline frameworks with permanent porosity (1)....
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...MOF-1001 [Zn4O(BPP34C10DA)3; BPP34C10DA = 4,4′-(2,5,8,11,14,16,19,22,25,28decaoxa-1,15(1,4)-dibenzenacyclooctacosaphane1(2),1(5)-diylbis(ethyne-2,1-diyl))dibenzoate] uses periodic crown ether receptors attached to the architectural framework; this endows the pore with active domains capable of molecular recognition of highly disordered guests in a stereoelectronically controlled fashion (Fig....
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...works inwhich single atomswere linked by ditopic coordinating linkers (1)....
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7,010 citations
"The Chemistry and Applications of M..." refers background in this paper
...MOFs can be used to support homogeneous catalysts, stabilize short-lived catalysts, perform size selectivity, and encapsulate catalysts within their pores (70)....
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6,922 citations
"The Chemistry and Applications of M..." refers background in this paper
...changing its underlying topology) in the design of MOFs with ultrahigh porosity and unusually large pore openings (5)....
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...One of the smallest isoreticular structures of MOF-5 is Zn4O(fumarate)3 (34); one of the largest is IRMOF-16 [Zn4O(TPDC)3; TPDC 2– = terphenyl-4,4′′-dicarboxylate] (5) (fig....
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6,778 citations
"The Chemistry and Applications of M..." refers background in this paper
...A major advance in the chemistry of MOFs came in 1999 when the synthesis, x-ray singlecrystal structure determination, and low-temperature, low-pressure gas sorption properties were reported for the first robust and highly porousMOF,MOF-5 (13)....
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