Journal ArticleDOI
The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
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TLDR
Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.Abstract:
Crystalline metal-organic frameworks (MOFs) are formed by reticular synthesis, which creates strong bonds between inorganic and organic units. Careful selection of MOF constituents can yield crystals of ultrahigh porosity and high thermal and chemical stability. These characteristics allow the interior of MOFs to be chemically altered for use in gas separation, gas storage, and catalysis, among other applications. The precision commonly exercised in their chemical modification and the ability to expand their metrics without changing the underlying topology have not been achieved with other solids. MOFs whose chemical composition and shape of building units can be multiply varied within a particular structure already exist and may lead to materials that offer a synergistic combination of properties.read more
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Journal ArticleDOI
Introduction to Metal–Organic Frameworks
Journal ArticleDOI
Luminescent metal–organic frameworks for chemical sensing and explosive detection
TL;DR: This review intends to provide an update of work published since then and focuses on the photoluminescence properties of MOFs and their possible utility in chemical and biological sensing and detection.
Journal ArticleDOI
Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design
TL;DR: This review will explore beyond the current focus on three-dimensional (3-D) lead(II) halide perovskites, to highlight the great chemical flexibility and outstanding potential of the broader class of 3-D and lower dimensional organic-based perovSKite family for electronic, optical, and energy-based applications as well as fundamental research.
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A metal–organic framework-derived bifunctional oxygen electrocatalyst
TL;DR: In this paper, a general approach for the synthesis of hollow frameworks of nitrogen-doped carbon nanotubes derived from metal-organic frameworks, which exhibit higher electrocatalytic activity and stability for oxygen reduction and evolution than commercial Pt/C catalysts, is presented.
References
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Journal ArticleDOI
A chromium terephthalate-based solid with unusually large pore volumes and surface area.
Gérard Férey,Gérard Férey,Caroline Mellot-Draznieks,Christian Serre,Franck Millange,Julien Dutour,Suzy Surblé,Irene Margiolaki +7 more
TL;DR: This crystal structure for porous chromium terephthalate, MIL-101, with large poresizes and surface area has potential as a nanomold for monodisperse nanomaterials, as illustrated here by the incorporation of Keggin polyanions within the cages.
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Hydrogen Storage in Microporous Metal-Organic Frameworks
Nathaniel L. Rosi,Juergen Eckert,Mohamed Eddaoudi,David T. Vodak,Jaheon Kim,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Inelastic neutron scattering spectroscopy of the rotational transitions of the adsorbed hydrogen molecules indicates the presence of two well-defined binding sites (termed I and II), which are associated with hydrogen binding to zinc and the BDC linker, respectively.
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Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites.
Norbert Stock,Shyam Biswas +1 more
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A homochiral metal-organic porous material for enantioselective separation and catalysis
TL;DR: The synthesis of a homochiral metal–organic porous material that allows the enantioselective inclusion of metal complexes in its pores and catalyses a transesterification reaction in an enantiOSElective manner is reported.
Journal ArticleDOI
Ultrahigh Porosity in Metal-Organic Frameworks
Hiroyasu Furukawa,Nakeun Ko,Yong Bok Go,Naoki Aratani,Sang Beom Choi,Eunwoo Choi,A. Oezguer Yazaydin,Randall Q. Snurr,Michael O'Keeffe,Jaheon Kim,Omar M. Yaghi +10 more
TL;DR: The synthesis of a MOF in which zinc centers are bridged with long, highly conjugated organic linkers, but in which the overall symmetry of the networks created prevents formation of interpenetrating networks is described.