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The Coordination and Bioinorganic Chemistry of Molybdenum

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The article was published on 2007-03-09. It has received 78 citations till now. The article focuses on the topics: Bioorganometallic chemistry & Bioinorganic chemistry.

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Journal ArticleDOI

Molybdenum(VI) complexes of a few pyrimidine derived ligands and the study of metal mediated C = N bond cleavage resulting in ligand transformation during complex formation

TL;DR: In this article, the Schiff base ligands HL1 and HL2 were used to synthesize dioxomolybdenum(VI) complexes, which are characterized by elemental analyses, electronic spectra, IR, 1H NMR, magnetic measurements, EPR and cyclic voltammetry.
Journal ArticleDOI

Metal complexes of antiuralethic drug: Synthesis, spectroscopic characterization and thermal study on allopurinol complexes

TL;DR: In this article, the allopurinol ligand (H2L; Alp (C5H4N4O)) was synthesized and characterized by microanalyses, magnetic susceptibility, conductance, infrared, electronic spectral and thermogravimetric (TGA/DTG) measurements.
Journal ArticleDOI

Spin-flip luminescence

TL;DR: In this paper , a review of spin-flip emitters is presented, with a brief introduction to ligand field theory as a framework to understand this phenomenon and outline prerequisites for efficient spin-FLIP emission including ligand fields strength, symmetry, intersystem crossing and common deactivation pathways.
Journal ArticleDOI

Recent developments in the study of molybdoenzyme models

TL;DR: The most recent model studies aimed to reproduce detailed features of the pterin–dithiolene ligand, both as the uncoordinated form and as a chelate coordinated to molybdenum are discussed.
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Chemical, electrochemical and structural studies of some cis -dioxomolybdenum(VI) complexes of two tridentate ONS chelating ligands

TL;DR: Several cis-dioxomolybdenum complexes of two tridentate ONS chelating ligands H 2L1 and H2L2 (obtained by condensation of S-benzyl and S-methyl dithiocarbazates with 2-hydroxyacetophenone) have been prepared and characterized as discussed by the authors.
References
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Hard and soft acids and bases

TL;DR: In this paper, the rate data for the generalized nucleophilic displacement reaction were reviewed, and the authors presented a method to estimate the rate of the generalized displacement reaction in terms of the number of nucleophiles.
Journal ArticleDOI

Alkyl and aryl derivatives of π-cyclopentadienyl compounds of chromium, molybdenum, tungsten, and iron

TL;DR: In this article, the preparation of alkyl and aryl π-cyclopentadienyl carbon monoxide or nitric oxide compounds of Cr, Mo, W, and Fe is described.
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