Book ChapterDOI
The Coordination and Bioinorganic Chemistry of Molybdenum
Edward I. Stiefel
- pp 1-223
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The article was published on 2007-03-09. It has received 78 citations till now. The article focuses on the topics: Bioorganometallic chemistry & Bioinorganic chemistry.read more
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Book ChapterDOI
EPR Studies of Xanthine Oxidoreductase and Other Molybdenum-Containing Hydroxylases
TL;DR: In this paper, a summary of early work establishing the different types of EPR signals manifested by the molybdenum centers of enzymes such as xanthine oxidoreductase and more recent studies, frequently employing more advanced EPR-related methods, which have contributed significantly to our understanding of the physical and electronic structures of the enzyme active site.
Journal ArticleDOI
Reaction Chemistry of the syn-[Mo2O2(μ-S)2(S2)(DMF)3] Complex with Cyanide and Catalytic Thiocyanate Formation.
Sigridur G. Suman,Sigridur G. Suman,Johanna M. Gretarsdottir,Paul E. Penwell,Jón Pétur Gunnarsson,Sindri Frostason,Sigridur Jonsdottir,Krishna K. Damodaran,Albert S. Hirschon +8 more
TL;DR: The approach to determine the number of cyanide ligands participating in the ligand exchange reaction by varying the stoichiometry and reaction temperature led to identification and isolation of tetranuclear complexes 2 and 5 and dinuclear complexes 3, 4, and 6.
Journal ArticleDOI
Cloud point extraction of 99Mo with Triton X-114
Swadesh Mandal,Susanta Lahiri +1 more
TL;DR: In this paper, the authors reported the cloud point extraction (CPE) extraction behavior of 99Mo in non-ionic Triton X-114 (TX-114), sodiumdodecyl sulphate (SDS)+ TX-114 and sodium diethyldithiocarbamate (DDTC)+TX- 114.
Journal ArticleDOI
Synthesis and characterization of asymmetric [Mo2O2(μ-S)2(S2)(L)] complexes (L = bipy, en, dien) and their heterogeneous reaction with propylene sulfide
TL;DR: In this article, the asymmetric dinuclear complexes, [Mo2O2(μ-S)2(S2)(L)] (1, L=bipyridine (bipy); 2, L =ethylene diamine (en), 3, L`=diethylenediamine (dien)) in facile ligand exchange reaction were obtained from DMF/ether solution as dark red plates and analyzed by X-ray diffraction.
Journal ArticleDOI
Microwave‐assisted synthesis of disulfides using tetrathiomolybdate: A step toward greener synthesis
TL;DR: An eco-friendly, efficient, and rapid synthetic procedure for disulfides using benzyl triethyl ammonium tetrathiomolybdate through microwave irradiation of solid support adsorbed reactants is reported in this paper.
References
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Journal ArticleDOI
Hard and soft acids and bases
TL;DR: In this paper, the rate data for the generalized nucleophilic displacement reaction were reviewed, and the authors presented a method to estimate the rate of the generalized displacement reaction in terms of the number of nucleophiles.
Journal ArticleDOI
Principles of structure, bonding, and reactivity for metal nitrosyl complexes
Journal ArticleDOI
The relative affinities of ligand atoms for acceptor molecules and ions
Journal ArticleDOI
Alkyl and aryl derivatives of π-cyclopentadienyl compounds of chromium, molybdenum, tungsten, and iron
T.S. Piper,G. Wilkinson +1 more
TL;DR: In this article, the preparation of alkyl and aryl π-cyclopentadienyl carbon monoxide or nitric oxide compounds of Cr, Mo, W, and Fe is described.