Book ChapterDOI
The Coordination and Bioinorganic Chemistry of Molybdenum
Edward I. Stiefel
- pp 1-223
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The article was published on 2007-03-09. It has received 78 citations till now. The article focuses on the topics: Bioorganometallic chemistry & Bioinorganic chemistry.read more
Citations
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Journal ArticleDOI
Molybdenum in natural waters: A review of occurrence, distributions and controls
TL;DR: The 2011 WHO Guidelines for Drinking-Water Quality (fourth edition) advised a health-based value of 70μg/L for Mo but this is no longer promulgated as a formal guideline value as WHO consider such concentrations to be rarely found in drinking water as discussed by the authors.
Journal ArticleDOI
Structure and Function of Xanthine Oxidoreductase
TL;DR: An overview of the current state of our understanding of the molybdenum-containing enzyme xanthine oxidoreductase is presented, with an emphasis on work done in the past five years.
Journal ArticleDOI
Synthetic approaches to the molybdenum sulfide materials
TL;DR: In this article, synthetic aspects of molybdenum sulfide-based materials were reviewed, with emphasis on the catalytic materials, and a number of preparation methods were critically compared, including molecular precursor decomposition, hydrothermal, soft chemistry aqueous, surfactant-aided, intercalation-exfoliation, and solid gas reactions.
Journal ArticleDOI
Reduction of Carbon Dioxide by a Molybdenum-Containing Formate Dehydrogenase: A Kinetic and Mechanistic Study.
TL;DR: The ability of Desulfovibrio desulfuricans formate dehydrogenase (DdFDH) to reduce carbon dioxide was kinetically and mechanistically characterized and a kinetic model of a hysteretic enzyme is proposed to interpret and predict the progress curves of the Dd FDH-catalyzed reactions.
Journal ArticleDOI
Synthesis and characterization of molybdenum complexes with bidentate Schiff base ligands within nanoreactors of MCM-41 as epoxidation catalysts
TL;DR: The mesoporous molecular sieve MCM-41 was covalently grafted with 3-aminopropyl trimethoxysilane (AmpMCM41) in this article.
References
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Journal ArticleDOI
Some ethylenediamine complexes of tervalent titanium, vanadium and molybdenum
TL;DR: In this article, the spectral and magnetic properties of the products have been investigated and their significance is discussed, and the spectral properties of these products are compared with those of the resulting animobasic halides MoX3(NH(CH2)2NH2.
Journal ArticleDOI
Molybdenum nitrosyl complexes containing bridging hydrazido-groups: X-ray analysis of the structure of {(π-C5H5)Mo(NO)I}2(µ-NNMe2)
W. George Kita,Jon A. McCleverty,Brian E. Mann,Duncan Seddon,George A. Sim,David I. Woodhouse +5 more
TL;DR: In this article, an X-ray cystallographic analysis showed that when X = I, R1= R2= Me, the molecule contained an asymmetric hydrazide group bridging two {(π-C5H5)Mo(NO)I} units; Mo(1) is bound to the terminal N atom and Mo(2) to both N atoms of the hydrazido ligand.
Journal ArticleDOI
Proton and electron transfer in molybdenum complexes: Implications for molybdenum enzymes☆
TL;DR: In this article, simple mechanistic schemes are presented which explain a number of features of the action of Mo in enzymes and it is suggested that Re complexes and Re substituted enzymes may provide useful complementary information in the study of Mo chemistry.
Journal ArticleDOI
The structure of a nitrogeno–molybdenum carbene chelate: π-C5H5(CO)2MoN(H)NC(CO2C2H5)COH
J. R. Knox,C. K. Prout +1 more
Journal ArticleDOI
Heptakis(alkyl isocyanide)molybdenum(II) complexes
TL;DR: In this paper, the synthesis of [Mo(CNR)7]X2(R = Me, X = I−; R = But, X= PF6−, I3−) compounds from Mo(CO)6 or Ag4[Mo(CN)8] is described; conductivity and spectral data suggest the presence of seven-coordinate molybdenum(II) dication in solution.