Book ChapterDOI
The Coordination and Bioinorganic Chemistry of Molybdenum
Edward I. Stiefel
- pp 1-223
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The article was published on 2007-03-09. It has received 78 citations till now. The article focuses on the topics: Bioorganometallic chemistry & Bioinorganic chemistry.read more
Citations
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Journal ArticleDOI
Molybdenum in natural waters: A review of occurrence, distributions and controls
TL;DR: The 2011 WHO Guidelines for Drinking-Water Quality (fourth edition) advised a health-based value of 70μg/L for Mo but this is no longer promulgated as a formal guideline value as WHO consider such concentrations to be rarely found in drinking water as discussed by the authors.
Journal ArticleDOI
Structure and Function of Xanthine Oxidoreductase
TL;DR: An overview of the current state of our understanding of the molybdenum-containing enzyme xanthine oxidoreductase is presented, with an emphasis on work done in the past five years.
Journal ArticleDOI
Synthetic approaches to the molybdenum sulfide materials
TL;DR: In this article, synthetic aspects of molybdenum sulfide-based materials were reviewed, with emphasis on the catalytic materials, and a number of preparation methods were critically compared, including molecular precursor decomposition, hydrothermal, soft chemistry aqueous, surfactant-aided, intercalation-exfoliation, and solid gas reactions.
Journal ArticleDOI
Reduction of Carbon Dioxide by a Molybdenum-Containing Formate Dehydrogenase: A Kinetic and Mechanistic Study.
TL;DR: The ability of Desulfovibrio desulfuricans formate dehydrogenase (DdFDH) to reduce carbon dioxide was kinetically and mechanistically characterized and a kinetic model of a hysteretic enzyme is proposed to interpret and predict the progress curves of the Dd FDH-catalyzed reactions.
Journal ArticleDOI
Synthesis and characterization of molybdenum complexes with bidentate Schiff base ligands within nanoreactors of MCM-41 as epoxidation catalysts
TL;DR: The mesoporous molecular sieve MCM-41 was covalently grafted with 3-aminopropyl trimethoxysilane (AmpMCM41) in this article.
References
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Journal ArticleDOI
Triangular dodecahedral stereochemistry of Mo(CH3NC)4(CN)4; an X-ray study
F. H. Cano,D. W. J. Cruickshank +1 more
Abstract: X-Ray diffraction shows that the co-ordination of eight carbon atoms about molybdenum is a slightly distorted triangular dodecahedron; the tungsten compound is isomorphous.
Journal ArticleDOI
Electron spin resonance in some molybdenum(V) halogeno-complexes
R. D. Dowsing,J. F. Gibson +1 more
TL;DR: In this paper, three paramagnetic species are shown to exist in hydrobromic acid solutions of molybdenum(V) at hydrogen bromide concentrations greater than 5·75M and two of these are detectable by electron spin resonance (e.s.r.) and are believed to be monomeric.
Journal ArticleDOI
The Use of Proton Magnetic Resonance in the Study of Complexones
TL;DR: The available literature data for the protonation of complexones and the formation of their complexes with diamagnetic and paramagnetic ions are reviewed in this paper, where a systematic and general account is given of studies on the equilibria and kinetics of complex formation and of the structures of the complexes.