Book ChapterDOI
The Coordination and Bioinorganic Chemistry of Molybdenum
Edward I. Stiefel
- pp 1-223
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The article was published on 2007-03-09. It has received 78 citations till now. The article focuses on the topics: Bioorganometallic chemistry & Bioinorganic chemistry.read more
Citations
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Journal ArticleDOI
Molybdenum in natural waters: A review of occurrence, distributions and controls
TL;DR: The 2011 WHO Guidelines for Drinking-Water Quality (fourth edition) advised a health-based value of 70μg/L for Mo but this is no longer promulgated as a formal guideline value as WHO consider such concentrations to be rarely found in drinking water as discussed by the authors.
Journal ArticleDOI
Structure and Function of Xanthine Oxidoreductase
TL;DR: An overview of the current state of our understanding of the molybdenum-containing enzyme xanthine oxidoreductase is presented, with an emphasis on work done in the past five years.
Journal ArticleDOI
Synthetic approaches to the molybdenum sulfide materials
TL;DR: In this article, synthetic aspects of molybdenum sulfide-based materials were reviewed, with emphasis on the catalytic materials, and a number of preparation methods were critically compared, including molecular precursor decomposition, hydrothermal, soft chemistry aqueous, surfactant-aided, intercalation-exfoliation, and solid gas reactions.
Journal ArticleDOI
Reduction of Carbon Dioxide by a Molybdenum-Containing Formate Dehydrogenase: A Kinetic and Mechanistic Study.
TL;DR: The ability of Desulfovibrio desulfuricans formate dehydrogenase (DdFDH) to reduce carbon dioxide was kinetically and mechanistically characterized and a kinetic model of a hysteretic enzyme is proposed to interpret and predict the progress curves of the Dd FDH-catalyzed reactions.
Journal ArticleDOI
Synthesis and characterization of molybdenum complexes with bidentate Schiff base ligands within nanoreactors of MCM-41 as epoxidation catalysts
TL;DR: The mesoporous molecular sieve MCM-41 was covalently grafted with 3-aminopropyl trimethoxysilane (AmpMCM41) in this article.
References
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Journal ArticleDOI
Structure of the Aqueous Pertechnetate Ion by Raman and Infrared Spectroscopy. Raman and Infrared Spectra of Crystalline KTcO4, KReO4, Na2MoO4, Na2WO4, Na2MoO4·2H2O, and Na2WO4·2H2O
R. H. Busey,O. L. Keller +1 more
TL;DR: The Raman crystal spectra of KTcO4, KReO4 and Na2MoO4 have been measured in the rock salt region as discussed by the authors, and the Raman aqueous spectra has been observed in the Nujol mulls of all the salts.
Journal ArticleDOI
Electron transfer spectra of hexahalide complexes
TL;DR: The electron transfer spectra of the chloro, bromo, and iodo complexes of Ru(III), Ru(IV), Rh(III) and Pb(IV) are studied and interpreted by group-theoretical methods as transitions of π (and at higher wave-numbers, σ) electrons, mainly localized in the ligands, to the available orbitals of even parity γ 5, γ 3 and γ 1, representing mainly d, d, and s electrons of the central ion as mentioned in this paper.
Journal ArticleDOI
Properties of Metal-to-Oxygen Multiple Bonds, Especially Molybdenum-to-Oxygen Bonds
F. A. Cotton,R. M. Wing +1 more
Journal ArticleDOI
The reduction of mono-coordinated molecular nitrogen to ammonia in a protic environment
TL;DR: THE AUTHORS have reduced ligating molecular nitrogen (dinitrogen) to ammonia in yields of up to 90% at a single metal site and this reaction was performed in a vacuum so that the evolved gases could be analysed and measured.