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The Coordination and Bioinorganic Chemistry of Molybdenum

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The article was published on 2007-03-09. It has received 78 citations till now. The article focuses on the topics: Bioorganometallic chemistry & Bioinorganic chemistry.

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Journal ArticleDOI

Molybdenum in natural waters: A review of occurrence, distributions and controls

TL;DR: The 2011 WHO Guidelines for Drinking-Water Quality (fourth edition) advised a health-based value of 70μg/L for Mo but this is no longer promulgated as a formal guideline value as WHO consider such concentrations to be rarely found in drinking water as discussed by the authors.
Journal ArticleDOI

Structure and Function of Xanthine Oxidoreductase

TL;DR: An overview of the current state of our understanding of the molybdenum-containing enzyme xanthine oxidoreductase is presented, with an emphasis on work done in the past five years.
Journal ArticleDOI

Synthetic approaches to the molybdenum sulfide materials

TL;DR: In this article, synthetic aspects of molybdenum sulfide-based materials were reviewed, with emphasis on the catalytic materials, and a number of preparation methods were critically compared, including molecular precursor decomposition, hydrothermal, soft chemistry aqueous, surfactant-aided, intercalation-exfoliation, and solid gas reactions.
Journal ArticleDOI

Reduction of Carbon Dioxide by a Molybdenum-Containing Formate Dehydrogenase: A Kinetic and Mechanistic Study.

TL;DR: The ability of Desulfovibrio desulfuricans formate dehydrogenase (DdFDH) to reduce carbon dioxide was kinetically and mechanistically characterized and a kinetic model of a hysteretic enzyme is proposed to interpret and predict the progress curves of the Dd FDH-catalyzed reactions.
Journal ArticleDOI

Synthesis and characterization of molybdenum complexes with bidentate Schiff base ligands within nanoreactors of MCM-41 as epoxidation catalysts

TL;DR: The mesoporous molecular sieve MCM-41 was covalently grafted with 3-aminopropyl trimethoxysilane (AmpMCM41) in this article.
References
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Journal ArticleDOI

Acetylacetonate complexes of molybdenum(V) and molybdenum(VI). I.

TL;DR: In this article, the ultraviolet and visible spectra of Mo 2 O 3 (C 5 H 7 O 2 ) 4 and MoO 2 (C 7 O 3 ) 2 have been obtained in a variety of solvents and the electronic transitions assigned.
Journal ArticleDOI

Formation of carbyne-like ligands by the protonation of isonitriles ligating electron-rich metal centres; X-ray structure of trans-[Mo(CNMe)2(Ph2PCH2CH2PPh2)]

TL;DR: The trans-[M(CNR)2(dpe)2] and trans-[Mo(CNMe)2dpe] as discussed by the authors ] compounds can be protonated at one or both nitrogen atoms giving carbyne-like ligands, but alkylated at only one.
Journal ArticleDOI

Crystal Spectra of Pentahalo Vanadyl and Molybdenyl Anions

TL;DR: In this article, the crystal spectra of some pentahalo complex ions VOX53 and MoOX52 were obtained and the 2B2→2B1 transition was assigned to the vanadyl stretching frequency.
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