Book ChapterDOI
The Coordination and Bioinorganic Chemistry of Molybdenum
Edward I. Stiefel
- pp 1-223
Reads0
Chats0
About:
The article was published on 2007-03-09. It has received 78 citations till now. The article focuses on the topics: Bioorganometallic chemistry & Bioinorganic chemistry.read more
Citations
More filters
Journal ArticleDOI
Molybdenum in natural waters: A review of occurrence, distributions and controls
TL;DR: The 2011 WHO Guidelines for Drinking-Water Quality (fourth edition) advised a health-based value of 70μg/L for Mo but this is no longer promulgated as a formal guideline value as WHO consider such concentrations to be rarely found in drinking water as discussed by the authors.
Journal ArticleDOI
Structure and Function of Xanthine Oxidoreductase
TL;DR: An overview of the current state of our understanding of the molybdenum-containing enzyme xanthine oxidoreductase is presented, with an emphasis on work done in the past five years.
Journal ArticleDOI
Synthetic approaches to the molybdenum sulfide materials
TL;DR: In this article, synthetic aspects of molybdenum sulfide-based materials were reviewed, with emphasis on the catalytic materials, and a number of preparation methods were critically compared, including molecular precursor decomposition, hydrothermal, soft chemistry aqueous, surfactant-aided, intercalation-exfoliation, and solid gas reactions.
Journal ArticleDOI
Reduction of Carbon Dioxide by a Molybdenum-Containing Formate Dehydrogenase: A Kinetic and Mechanistic Study.
TL;DR: The ability of Desulfovibrio desulfuricans formate dehydrogenase (DdFDH) to reduce carbon dioxide was kinetically and mechanistically characterized and a kinetic model of a hysteretic enzyme is proposed to interpret and predict the progress curves of the Dd FDH-catalyzed reactions.
Journal ArticleDOI
Synthesis and characterization of molybdenum complexes with bidentate Schiff base ligands within nanoreactors of MCM-41 as epoxidation catalysts
TL;DR: The mesoporous molecular sieve MCM-41 was covalently grafted with 3-aminopropyl trimethoxysilane (AmpMCM41) in this article.
References
More filters
Journal ArticleDOI
Evidence for the existence of a fully reduced state of molybdoferredoxin during the functioning of nitrogenase, and the order of electron transfer from reduced ferredoxin.
TL;DR: Molybdoferredoxin from Clostridium pasteurianum W5 was studied under conditions where the nitrogenase system was turning over and molybd oferredoxin was known to be ∼90% in the EPR-silent state and a reduction scheme for N2 fixation is proposed.
Journal ArticleDOI
Dithiocarbamato derivatives of allyl molybdenum nitrosyls
Neil A. Bailey,W. George Kita,Jon A. McCleverty,Alan J. Murray,Brian E. Mann,N. W. ‘Joe’ Walker +5 more
TL;DR: In this paper, the structures of the latter and of the former were established by X-ray crystallography, obtained from [(η5-C5H5)Mo(NO)(H2CCH:CH2SC(:S)NMe2}] respectively.
Journal ArticleDOI
Dimeres molybdän(II)-bis(dimethylphosphonium-dimethylid) Mo2[(CH2)2P(CH3)2]4
TL;DR: In this paper, the diamagnetic diamagnetic Mo II [(CH 2 ) 2 P(CH 3 ) 2 ] 4 has been prepared by direct reaction of the metallated ylid with MoCl 3 (THF) 3 and also by reaction of Li 4 Mo 2 (CH 3 ), 8 ·4THF with [(CH 3 ] 4 P]Cl.
Journal ArticleDOI
A molybdenum phthalocyanine
H. A. O. Hill,M. M. Norgett +1 more
TL;DR: Phthalocyanine-oxymolybdenum(IV), MoOC32H16N8, has been prepared as an air-stable, diamagnetic complex as mentioned in this paper.
Journal ArticleDOI
Arene molybdenum chemistry: some π-allyl, hydrido, and dinitrogen derivatives
M. L. H. Green,W. E. Silverthorn +1 more
TL;DR: Treatment of the new compound C6H6Mo(π-C3H5)(PPh3)Cl with sodium borohydride forms the dihydride C 6H 6Mo(PPh 3)2H2 which reacts readily with nitrogen gas forming the binuclear dinitrogen complex [C6H 6 Mo(P Ph3)2]2N2 as mentioned in this paper.