The Crystal Structure of Tellurium Di(morpholyldithiocarbamate).
About: This article is published in Acta Chemica Scandinavica.The article was published on 1970-01-01 and is currently open access. It has received 28 citations till now. The article focuses on the topics: Tellurium & Crystal structure.
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66 citations
TL;DR: In this article, a survey of the literature of tellurium(II)/(IV) 1,1-dithiolates (dithiocarbamate, xanthate, dithiophosphate, or dithIophosphinate) is presented.
44 citations
01 Jun 1972
TL;DR: The crystal and molecular structure of triphenylphosphine (N,N-diethyldithio-carbamato) gold(I), (C6H5)3PAuSSCN(C2H5), has been determined by three-dimensional X-ray methods.
Abstract: The crystal and molecular structure of triphenylphosphine (N,N-diethyldithio-carbamato) gold(I), (C6H5)3PAuSSCN(C2H5)2, has been determined by three-dimensional X-ray methods. The compound crystallizes in the monoclinic space groupP21/c witha = 13·547(1),b = 12·277(1),c = 14·013(1) A, β = 90·81(1) ° andZ = 4. Three-dimensional intensity data were collected on an automatic diffracto-meter. Atomic parameters were refined by full-matrix least-squares methods to a conventionalR value of 0·04 for 2318 non-zero observed reflexions. In this complex the diethyldithiocarbamate moiety acts as a monodentate ligand, the
double-bond distance being 1·68(1) A and the
bond involving the sulphur atom that is coordinated to the gold atom being 1·75(1) A. The gold atom is linearly coordinated, the
angle being 175·7(1) ° and the
and
distances being 2·338(3) and 2·251(3) A, respectively.
39 citations
TL;DR: In this article, the crystal structures of (1,10-phenanthroline) and (2,2′-bipyridine)bis(piperidinecarbodithioato-S,S,s′)cadmium(II), [Cd(pipdtc)2(1, 10-phen)] adducts were prepared and crystal structures are reported.
34 citations
TL;DR: In this article, the crystal structure of 2 is reported and the Zn-S distances in 2 are longer than those in Zn(dtc)2 complexes and S2p binding energies show a significant reduction in value compared to the parent dithiocarbmate [Zn(pipdtc)-2](3), indicating the weakening of Zn−S bond on adduct formation.
31 citations