Journal ArticleDOI
The crystal structure of the blue potassium molybdenum bronze, K0.28MoO3
J. Graham,A. D. Wadsley +1 more
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This article is published in Acta Crystallographica.The article was published on 1966-01-01. It has received 136 citations till now. The article focuses on the topics: Molybdenum bronze & Potassium.read more
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Book ChapterDOI
Mixed Valence Chemistry-A Survey and Classification
Melvin B. Robin,Peter Day +1 more
TL;DR: In this article, a review is concerned with the neglected class of inorganic compounds, which contain ions of the same element in two different formal states of oxidation, and a number of references cite that many individual examples of this class have been studied, yet they have very rarely been treated as a class, and there has never before, to our knowledge, been a systematic attempt to classify their properties in terms of their electronic and molecular structures.
Journal ArticleDOI
Electronic structure and properties of solids
TL;DR: In this paper, some of the challenges facing scientists in the area of the electronic structure and properties of solids are reviewed, and the importance of going beyond the raw output of the calculation and understanding where the result originates is stressed.
Journal ArticleDOI
Electronic crystals: an experimental overview
TL;DR: In this paper, the static and dynamic properties of spontaneous superstructures formed by electrons are reviewed, and a special attention is paid to the collective effects in pinning and sliding of these structures, and the glassy properties at low temperature.
Journal ArticleDOI
The mutual influence of ligands in transition metal coordination compounds with multiple metal-ligand bonds
Journal ArticleDOI
Evidence for a Peierls transition in the blue bronzes K0.30MoO 3 and Rb0.30MoO3
TL;DR: In this article, the phase transition of the blue bronzes can be viewed as a Peierls distortion and the anisotropic electrical resistivity is consistent with a quasi one-dimensional conduction band built on hybridized molybdenum 4d and oxygen pπ orbitals.