The Dieckmann Condensation (Including the Thorpe‐Ziegler Condensation)
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...In dynamical approaches, time-dependent simulations are biased to increase the probability of rare events by artificial attractive interatomic forces 5 or by performing simulations under high-energy conditions.(6,7) Alternatively, reaction paths can be generated by “walking” the potential energy surface between products and reactants, probing only necessary dimensions of the full surface....
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Cites background from "The Dieckmann Condensation (Includi..."
...First reported in 1887,(224) the Claisen condensation plays an important role in synthetic organic chemistry.(225-228) The Claisen condensation involves the enolate of an ester undergoing a reversible nucleophilic addition / elimination reaction with another equivalent of ester in the presence of excess base....
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References
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