Journal ArticleDOI
The electrical double layer in molten salts: Part 2. The double-layer capacitance
A.D. Graves,D. Inman +1 more
Reads0
Chats0
TLDR
In this article, the double-layer capacitance of the liquid metal/molten alkali halide interphase is discussed and an equation for the temperature dependence of the potential at which the transition from ideally polarisable to ideally reversible behavior occurs is given.About:
This article is published in Journal of Electroanalytical Chemistry.The article was published on 1970-05-01. It has received 101 citations till now. The article focuses on the topics: Differential capacitance & Ideally polarizable electrode.read more
Citations
More filters
Journal ArticleDOI
Structure and nanostructure in ionic liquids.
Journal ArticleDOI
Ionic Liquids at Electrified Interfaces
TL;DR: One of the advantages of RTILs as compared to their high-temperature molten salt (HTMS) “sister-systems” is that the dissolved molecules are not imbedded in a harsh high temperature environment which could be destructive for many classes of fragile (organic) molecules.
Journal ArticleDOI
Differential Capacitance of the Electrical Double Layer in Imidazolium-Based Ionic Liquids: Influence of Potential, Cation Size, and Temperature
TL;DR: In this paper, the interfaces formed at glassy carbon electrodes in three low-temperature ionic liquids (1-methyl-3-ethylimidazolium chloride, emimCl, bmimCl; and 1-methyl 3-hexy-limidaxolium-chloride (HmCl), hmCl) were investigated by cyclic voltammetry and impedance spectroscopy.
Journal ArticleDOI
Surface Structure at the Ionic Liquid−Electrified Metal Interface
TL;DR: The results present a view of the ionic liquid-metal electrode interface having a very thin "double layer" structure where the ions form a single layer at the surface to screen the electrode charge, and raise many other fundamental questions as to the detailed nature of the interfacial structure and interpretations of both electrochemical and spectroscopic data.
Journal ArticleDOI
Double Layer Structure of Ionic Liquids at the Au(111) Electrode Interface: An Atomic Force Microscopy Investigation
TL;DR: In this paper, the double layer structure of two ionic liquids (ILs), 1-butyl-1-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate ([Py1,4]FAP) and 1-ethyl-3-methylimidazolium triscane (EMIm) FAP at the polarized Au(111) electrode interface is probed using atomic force microscopy force measurements.
References
More filters
Journal ArticleDOI
The Structure of the Electrical Double Layer at the Metal-Solution Interface
Journal ArticleDOI
Electrode Processes without a Priori Separation of Double-Layer Charging
Relaxation electrode processes without a priori separation of double layer charging.
TL;DR: In this paper, the theory of relaxation electrode processes is developed on the basis of three, previously reported, general equations for a linearized current-overvoltage characteristic and for the following perturbations: single step galvanostatic, double step galvanization, coulostatic decay with charge injection either by a square current pulse of a delta-function pulse, and single step potentiostatic.
Journal ArticleDOI
The electrical double layer in molten salts
TL;DR: In this article, a relationship between the potential of zero charge of a metal in contact with an electrolyte and the work function of the metal is derived and discussed with the help of data for aqueous and molten electrolyte systems.