The electronic properties of graphene

doi:10.1103/REVMODPHYS.81.109

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The electronic properties of graphene

Journal Article•DOI•

The electronic properties of graphene

A. H. Castro Neto¹, Francisco Guinea², Nuno M. R. Peres³, Kostya S. Novoselov⁴, Andre K. Geim⁴ - Show less +1 more•Institutions (4)

Boston University¹, Spanish National Research Council², University of Minho³, University of Manchester⁴

14 Jan 2009-Reviews of Modern Physics (American Physical Society)-Vol. 81, Iss: 1, pp 109-162

TL;DR: In this paper, the basic theoretical aspects of graphene, a one-atom-thick allotrope of carbon, with unusual two-dimensional Dirac-like electronic excitations, are discussed.

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Abstract: This article reviews the basic theoretical aspects of graphene, a one-atom-thick allotrope of carbon, with unusual two-dimensional Dirac-like electronic excitations. The Dirac electrons can be controlled by application of external electric and magnetic fields, or by altering sample geometry and/or topology. The Dirac electrons behave in unusual ways in tunneling, confinement, and the integer quantum Hall effect. The electronic properties of graphene stacks are discussed and vary with stacking order and number of layers. Edge (surface) states in graphene depend on the edge termination (zigzag or armchair) and affect the physical properties of nanoribbons. Different types of disorder modify the Dirac equation leading to unusual spectroscopic and transport properties. The effects of electron-electron and electron-phonon interactions in single layer and multilayer graphene are also presented.

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Journal Article•DOI•

The GW Compendium: A Practical Guide to Theoretical Photoemission Spectroscopy.

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Dorothea Golze¹, Marc Dvorak¹, Patrick Rinke¹•Institutions (1)

Aalto University¹

09 Jul 2019-Frontiers in Chemistry

TL;DR: The GW approximation in electronic structure theory has become a widespread tool for predicting electronic excitations in chemical compounds and materials in the realm of theoretical spectroscopy as mentioned in this paper, which can be attributed to many factors: favorable scaling with respect to system size, a formal interpretation for charged excitation energies, the importance of dynamical screening in real systems, and its practical combination with other theories.

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Abstract: The GW approximation in electronic structure theory has become a widespread tool for predicting electronic excitations in chemical compounds and materials In the realm of theoretical spectroscopy, the GW method provides access to charged excitations as measured in direct or inverse photoemission spectroscopy The number of GW calculations in the past two decades has exploded with increased computing power and modern codes The success of GW can be attributed to many factors: favorable scaling with respect to system size, a formal interpretation for charged excitation energies, the importance of dynamical screening in real systems, and its practical combination with other theories In this review, we provide an overview of these formal and practical considerations We expand, in detail, on the choices presented to the scientist performing GW calculations for the first time We also give an introduction to the many-body theory behind GW, a review of modern applications like molecules and surfaces, and a perspective on methods which go beyond conventional GW calculations This review addresses chemists, physicists and material scientists with an interest in theoretical spectroscopy It is intended for newcomers to GW calculations but can also serve as an alternative perspective for experts and an up-to-date source of computational techniques

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208 citations

Journal Article•DOI•

Carbon Nanomaterials in Different Dimensions for Electrochemical Energy Storage

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Jiangfeng Ni¹, Yan Li²•Institutions (2)

Soochow University (Suzhou)¹, Peking University²

01 Sep 2016-Advanced Energy Materials

TL;DR: Carbon nanomaterials including fullerenes, carbon nanotubes, graphene and their assemblies represent a unique type of materials in diverse formats and dimensions, which are essentially required for vari-ous electrochemical energy storage (EES) systems such as Li-ion batteries, supercapacitors, and redox flow cells as mentioned in this paper.

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Abstract: Carbon nanomaterials including fullerenes, carbon nanotubes, graphene, and their assemblies represent a unique type of materials in diverse formats and dimensions. They feature a large surface area, superior conductivity, fast charge transport, and intrinsic stability, which are essentially required for various electrochemical energy storage (EES) systems such as Li-ion batteries, supercapacitors, and redox flow cells. The scaled-up and reliable production and assembly of carbon nanomaterials is a prerequisite for the development of carbon nanomaterial-based EES devices. In this progress report, the preparation of carbon nanostructures and the state-of-the-art applications of carbon nanomaterials with different dimensions in versatile EES systems are summarized. The importance of the synergetic effect induced by interactions between nanocarbons and active electrode species is highlighted. The main challenges and prospects in this field are also discussed.

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208 citations

Journal Article•DOI•

Observation of novel edge states in photonic graphene

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Mikael C. Rechtsman, Yonatan Plotnik, Daohong Song, Matthias Heinrich, Julia M. Zeuner, Stefan Nolte, Natalia Malkova, Jingjun Xu, Alexander Szameit, Zhigang Chen, Mordechai Segev - Show less +7 more

19 Oct 2012-arXiv: Mesoscale and Nanoscale Physics

TL;DR: In this article, the edge states on both the zig-zag and bearded edges of a photonic honeycomb lattice of carbon atoms were directly image and measured their dispersion properties, and most importantly, one residing on the bearded edge which was unknown and cannot be explained through conventional tight-binding theory.

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Abstract: The intriguing properties of graphene, a two-dimensional material composed of a honeycomb lattice of carbon atoms, have attracted a great deal of interest in recent years. Specifically, the fact that electrons in graphene behave as massless relativistic particles gives rise to unconventional phenomena such as Klein tunneling, the anomalous quantum Hall effect, and strain-induced pseudo-magnetic fields. Graphene edge states play a crucial role in the understanding and use of these electronic properties. However, the coarse or impure nature of the edges hampers the ability to directly probe the edge states and their band structure. Perhaps the best example is the edge states on the bearded edge (also called the Klein edge) that have thus far never been observed - because such an edge is unstable in graphene. Here, we use the optical equivalent of graphene - a photonic honeycomb lattice - to experimentally and theoretically study edge states and their properties. We directly image the edge states on both the zig-zag and bearded edges of this photonic graphene, measure their dispersion properties, and most importantly, find a new type of edge state: one residing on the bearded edge which was unknown and cannot be explained through conventional tight-binding theory. Such a new edge state lies near the van-Hove singularity in the edge band structure and can be classified as a Tamm state lacking any surface defect. Our photonic system offers the opportunity to probe new graphene-related phenomena that are difficult or impossible to access in conventional carbon-based graphene. Edge states in graphene-type structures play the central role in achieving photonic topological insulation, in which light can propagate along the edges of photonic structures without any parasitic scattering whatsoever.

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207 citations

Superballistic flow of viscous electron fluid through graphene constrictions

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Denis A. Bandurin, Roshan Krishna Kumar, Yang Cao, Francesco M. D. Pellegrino, Marco Polini, Leonid Levitov, Andre K. Geim, Denis Bandurin Team - Show less +4 more

01 Jan 2018

TL;DR: In this paper, the authors studied electron transport through graphene constrictions and showed that their conductance below 150 K increases with increasing temperature, in stark contrast to the metallic character of doped graphene.

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Abstract: Graphene systems are clean platforms for studying electron–electron (e–e) collisions. Electron transport in graphene constrictions is now found to behave anomalously due to e–e interactions: conductance values exceed the maximum free-electron value. Electron–electron (e–e) collisions can impact transport in a variety of surprising and sometimes counterintuitive ways1,2,3,4,5,6. Despite strong interest, experiments on the subject proved challenging because of the simultaneous presence of different scattering mechanisms that suppress or obscure consequences of e–e scattering7,8,9,10,11. Only recently, sufficiently clean electron systems with transport dominated by e–e collisions have become available, showing behaviour characteristic of highly viscous fluids12,13,14. Here we study electron transport through graphene constrictions and show that their conductance below 150 K increases with increasing temperature, in stark contrast to the metallic character of doped graphene15. Notably, the measured conductance exceeds the maximum conductance possible for free electrons16,17. This anomalous behaviour is attributed to collective movement of interacting electrons, which ‘shields’ individual carriers from momentum loss at sample boundaries18,19. The measurements allow us to identify the conductance contribution arising due to electron viscosity and determine its temperature dependence. Besides fundamental interest, our work shows that viscous effects can facilitate high-mobility transport at elevated temperatures, a potentially useful behaviour for designing graphene-based devices.

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207 citations

Journal Article•DOI•

Strain effect on the optical conductivity of graphene

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Francesco M. D. Pellegrino, Giuseppe G. N. Angilella, Renato Pucci¹•Institutions (1)

University of Catania¹

12 Jan 2010-Physical Review B

TL;DR: In this article, the dependence of the electronic band structure and of the optical conductivity of a graphene single layer on the modulus and direction of applied uniaxial strain was studied.

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Abstract: Within the tight-binding approximation, we study the dependence of the electronic band structure and of the optical conductivity of a graphene single layer on the modulus and direction of applied uniaxial strain. While the Dirac-cone approximation, albeit with a deformed cone, is robust for sufficiently small strain, band dispersion linearity breaks down along a given direction, corresponding to the development of anisotropic massive low-energy excitations. We recover a linear behavior of the low-energy density of states, as long as the cone approximation holds, while a band gap opens for sufficiently intense strain, for almost all, generic strain directions. This may be interpreted in terms of an electronic topological transition, corresponding to a change in topology of the Fermi line, and to the merging of two inequivalent Dirac points as a function of strain. We propose that these features may be observed in the frequency dependence of the longitudinal-optical conductivity in the visible range, as a function of strain modulus and direction, as well as of field orientation.

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207 citations

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Journal Article•DOI•

Electric Field Effect in Atomically Thin Carbon Films

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Kostya S. Novoselov¹, Andre K. Geim¹, Sergey V. Morozov, Da Jiang¹, Y. Zhang¹, S. V. Dubonos, Irina V. Grigorieva¹, A. A. Firsov - Show less +4 more•Institutions (1)

University of Manchester¹

22 Oct 2004-Science

TL;DR: Monocrystalline graphitic films are found to be a two-dimensional semimetal with a tiny overlap between valence and conductance bands and they exhibit a strong ambipolar electric field effect.

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Abstract: We describe monocrystalline graphitic films, which are a few atoms thick but are nonetheless stable under ambient conditions, metallic, and of remarkably high quality. The films are found to be a two-dimensional semimetal with a tiny overlap between valence and conductance bands, and they exhibit a strong ambipolar electric field effect such that electrons and holes in concentrations up to 10 13 per square centimeter and with room-temperature mobilities of ∼10,000 square centimeters per volt-second can be induced by applying gate voltage.

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55,532 citations

"The electronic properties of graphe..." refers background in this paper

...Be ause the DC magnetotransport properties ofgraphene are normally measured with the possibilityof tuning its ele troni density by a gate potential(Novoselov et al., 2004), it is important to ompute the ondu tivity kernel, sin e this has dire t experimentalrelevan e....
[...]
...The same polarizability describes the screening of an external field perpendicular to the layers, like the one induced by a gate in electrically doped systems (Novoselov et al., 2004)....
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...Because the DC magnetotransport properties of graphene are normally measured with the possibility of tuning its electronic density by a gate potential (Novoselov et al., 2004), it is important to compute the conductivity kernel, since this has direct experimental relevance....
[...]
...…studies of graphene sta ks have showed that, within reasing number of layers, the system be omes in reas-ingly metalli ( on entration of harge arriers at zero en-ergy gradually in reases), and there appear several typesof ele tron-and-hole-like arries (Morozov et al., 2005;Novoselov et al., 2004)....
[...]
...The same polarizabilitydes ribes the s reening of an external eld perpendi ularto the layers, like the one indu ed by a gate in ele tri- ally doped systems (Novoselov et al., 2004)....
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Journal Article•DOI•

The rise of graphene

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Andre K. Geim¹, Kostya S. Novoselov¹•Institutions (1)

University of Manchester¹

01 Mar 2007-Nature Materials

TL;DR: Owing to its unusual electronic spectrum, graphene has led to the emergence of a new paradigm of 'relativistic' condensed-matter physics, where quantum relativistic phenomena can now be mimicked and tested in table-top experiments.

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Abstract: Graphene is a rapidly rising star on the horizon of materials science and condensed-matter physics. This strictly two-dimensional material exhibits exceptionally high crystal and electronic quality, and, despite its short history, has already revealed a cornucopia of new physics and potential applications, which are briefly discussed here. Whereas one can be certain of the realness of applications only when commercial products appear, graphene no longer requires any further proof of its importance in terms of fundamental physics. Owing to its unusual electronic spectrum, graphene has led to the emergence of a new paradigm of 'relativistic' condensed-matter physics, where quantum relativistic phenomena, some of which are unobservable in high-energy physics, can now be mimicked and tested in table-top experiments. More generally, graphene represents a conceptually new class of materials that are only one atom thick, and, on this basis, offers new inroads into low-dimensional physics that has never ceased to surprise and continues to provide a fertile ground for applications.

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35,293 citations

"The electronic properties of graphe..." refers background in this paper

...As the current status of the experiment and potential applications have recently been reviewed (Geim and Novoselov, 2007), in this article we mostly concentrate on the theory and more technical aspects of electronic properties of this exciting new material....
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...As the urrent status of the experimentand potential appli ations have re ently been reviewed(Geim and Novoselov, 2007), in this arti le we mostly on entrate on the theory and more te hni al aspe ts ofele troni properties of this ex iting new material....
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...It has also been suggested that Coulomb intera tionsare onsiderably enhan ed in smaller geometries, su has graphene quantum dots (Milton Pereira Junior et al.,2007), leading to unusual Coulomb blo kade e e ts 4(Geim and Novoselov, 2007) and perhaps to magneti phenomena su h as the Kondo e e t....
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...…most versatile systems in ondensedmatter resear h.Besides the unusual basi properties, graphene hasthe potential for a large number of appli ations(Geim and Novoselov, 2007), from hemi al sensors(Chen et al., 2007 ; S hedin et al., 2007) to transistors(Nilsson et al., 2007b; Oostinga et al.,…...
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...Besides the unusual basic properties, graphene has the potential for a large number of applications (Geim and Novoselov, 2007), from chemical sensors (Chen et al....
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Book•

Theory of elasticity

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Stephen P. Timoshenko, James Norman Goodier

01 Jan 1934

TL;DR: The theory of the slipline field is used in this article to solve the problem of stable and non-stressed problems in plane strains in a plane-strain scenario.

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Abstract: Chapter 1: Stresses and Strains Chapter 2: Foundations of Plasticity Chapter 3: Elasto-Plastic Bending and Torsion Chapter 4: Plastic Analysis of Beams and Frames Chapter 5: Further Solutions of Elasto-Plastic Problems Chapter 6: Theory of the Slipline Field Chapter 7: Steady Problems in Plane Strain Chapter 8: Non-Steady Problems in Plane Strain

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20,724 citations

Journal Article•DOI•

Two-dimensional gas of massless Dirac fermions in graphene

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Kostya S. Novoselov¹, A. K. Geim¹, Sergey V. Morozov, Da Jiang¹, Mikhail I. Katsnelson², Irina V. Grigorieva¹, S. V. Dubonos, A. A. Firsov - Show less +4 more•Institutions (2)

University of Manchester¹, Radboud University Nijmegen²

10 Nov 2005-Nature

TL;DR: This study reports an experimental study of a condensed-matter system (graphene, a single atomic layer of carbon) in which electron transport is essentially governed by Dirac's (relativistic) equation and reveals a variety of unusual phenomena that are characteristic of two-dimensional Dirac fermions.

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Abstract: Quantum electrodynamics (resulting from the merger of quantum mechanics and relativity theory) has provided a clear understanding of phenomena ranging from particle physics to cosmology and from astrophysics to quantum chemistry. The ideas underlying quantum electrodynamics also influence the theory of condensed matter, but quantum relativistic effects are usually minute in the known experimental systems that can be described accurately by the non-relativistic Schrodinger equation. Here we report an experimental study of a condensed-matter system (graphene, a single atomic layer of carbon) in which electron transport is essentially governed by Dirac's (relativistic) equation. The charge carriers in graphene mimic relativistic particles with zero rest mass and have an effective 'speed of light' c* approximately 10(6) m s(-1). Our study reveals a variety of unusual phenomena that are characteristic of two-dimensional Dirac fermions. In particular we have observed the following: first, graphene's conductivity never falls below a minimum value corresponding to the quantum unit of conductance, even when concentrations of charge carriers tend to zero; second, the integer quantum Hall effect in graphene is anomalous in that it occurs at half-integer filling factors; and third, the cyclotron mass m(c) of massless carriers in graphene is described by E = m(c)c*2. This two-dimensional system is not only interesting in itself but also allows access to the subtle and rich physics of quantum electrodynamics in a bench-top experiment.

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18,958 citations

"The electronic properties of graphe..." refers background or methods in this paper

...This amazing re-sult has been observed experimentally (Novoselov et al.,2005a; Zhang et al., 2005) as shown in Fig.20....
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...Adapted from(Novoselov et al., 2005a)....
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...Adapted from (Novoselov et al.,2005a).and hen e σxy,inc. = I/VH = ±4Ne2/h, whi h is thenaive expe tation....
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...The period of os illations ∆n = 4B/Φ0,where B is the applied eld and Φ0 is the ux quantum(Novoselov et al., 2005a).or equivalently: (Oσ+ + O†σ−)φ = (2E/ωc)φ , (100)where σ± = σx ± iσy, and we have de ned the dimen-sionless length s ale: ξ = y ℓB − ℓBk , (101)and 1D harmoni os illator operators: O =…...
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...…invery unusual ways when ompared to ordinary ele tronsif subje ted to magneti elds, leading to new physi alphenomena (Gusynin and Sharapov, 2005; Peres et al.,2006 ) su h as the anomalous integer quantum Hall ef-fe t (IQHE) measured experimentally (Novoselov et al.,2005a; Zhang et al., 2005)....
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