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The electronic properties of graphene

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TLDR
In this paper, the basic theoretical aspects of graphene, a one-atom-thick allotrope of carbon, with unusual two-dimensional Dirac-like electronic excitations, are discussed.
Abstract
This article reviews the basic theoretical aspects of graphene, a one-atom-thick allotrope of carbon, with unusual two-dimensional Dirac-like electronic excitations. The Dirac electrons can be controlled by application of external electric and magnetic fields, or by altering sample geometry and/or topology. The Dirac electrons behave in unusual ways in tunneling, confinement, and the integer quantum Hall effect. The electronic properties of graphene stacks are discussed and vary with stacking order and number of layers. Edge (surface) states in graphene depend on the edge termination (zigzag or armchair) and affect the physical properties of nanoribbons. Different types of disorder modify the Dirac equation leading to unusual spectroscopic and transport properties. The effects of electron-electron and electron-phonon interactions in single layer and multilayer graphene are also presented.

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Review of CVD Synthesis of Graphene

TL;DR: The Spanish MICINN Project as mentioned in this paper was funded by the European Union Seventh Framework Programme under grant agreement n°604391 Graphene Flagship under grant number CSD2008-00023.
Journal ArticleDOI

Strain engineering in semiconducting two-dimensional crystals

TL;DR: An overview of the recent progress to control the optical and electronics properties of 2D crystals, by means of strain engineering, on semiconducting layered materials, with especial emphasis in transition metal dichalcogenides (MoS2, WS2, MoSe2 and WSe2).
Journal ArticleDOI

Growth of graphene on Ir(111)

TL;DR: In this paper, two growth methods for graphene on Ir(111), namely temperature programmed growth (TPG) and direct exposure of the hot substrate at 870-1320 K (CVD), are investigated in detail by scanning tunneling microscopy.
Journal ArticleDOI

Advanced rechargeable aluminium ion battery with a high-quality natural graphite cathode

TL;DR: Two different intercalation processes involving chloroaluminate anions at the two discharging plateaus are shown, while C–Cl bonding on the surface, or edges of natural graphite, is found using X-ray absorption spectroscopy, and theoretical calculations are employed to investigate the intercalated behaviour of choloraluminateAnions in the graphite electrode.
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Surface-Enhanced Raman Spectroscopy of Graphene

TL;DR: Graphene provides the ideal prototype two-dimensional test material to investigate surface-enhanced Raman scattering (SERS), and the 2d nature of graphene allows for a closed-form description of the Raman enhancement, which scales with the nanoparticle cross section, the fourth power of the Mie enhancement, in agreement with experiments.
References
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Journal ArticleDOI

Electric Field Effect in Atomically Thin Carbon Films

TL;DR: Monocrystalline graphitic films are found to be a two-dimensional semimetal with a tiny overlap between valence and conductance bands and they exhibit a strong ambipolar electric field effect.
Journal ArticleDOI

The rise of graphene

TL;DR: Owing to its unusual electronic spectrum, graphene has led to the emergence of a new paradigm of 'relativistic' condensed-matter physics, where quantum relativistic phenomena can now be mimicked and tested in table-top experiments.
Book

Theory of elasticity

TL;DR: The theory of the slipline field is used in this article to solve the problem of stable and non-stressed problems in plane strains in a plane-strain scenario.
Journal ArticleDOI

Two-dimensional gas of massless Dirac fermions in graphene

TL;DR: This study reports an experimental study of a condensed-matter system (graphene, a single atomic layer of carbon) in which electron transport is essentially governed by Dirac's (relativistic) equation and reveals a variety of unusual phenomena that are characteristic of two-dimensional Dirac fermions.
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