The hydrogen bond in the solid state.
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"The hydrogen bond in the solid stat..." refers background in this paper
...The idea that there is a more or less strict relationship between bond length and TMbond order∫ or TMvalence∫ s dates back to Pauling.[3] Several expressions for s f(d) have been proposed,[149, 150] but still the most popular one is Pauling×s exponential relationship [Eq....
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...More elaborate studies and clear general concepts were published from the 1920s on, with pioneering roles usually attributed to Latimer and Rodebush, Huggins, and Pauling....
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...The idea that there is a more or less strict relationship between bond length and ™bond order∫ or ™valence∫ s dates back to Pauling....
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"The hydrogen bond in the solid stat..." refers background or methods in this paper
...Strong, moderate, and weak hydrogen bonds following the classification of Jeffrey.[6] The numerical data are guiding values only....
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...The hydrogen bond is a complex interaction composed of several constituents that are different in their natures.[6, 7]...
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...leads to 1H downfield shifts that are correlated with the length of the hydrogen bond.[6, 56] Thus, NMR shift data can be used to estimate lengths of hydrogen bonds (Figure 5)....
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...Over 25% of all O H ¥¥¥O hydrogen bonds in carbohydrates are multifurcated, and this fraction is even higher in amino acids.[6]...
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...Consequently, the arrangements in Scheme 2b and 2c may be called TMthree-∫ and TMfourcentered∫ hydrogen bonds, respectively.[5, 6] This terminology is logical, but leads to confusion from the point of view of regarding hydrogen bonds O H ¥¥¥O as TMthree-center fourelectron∫ interactions, where the H-atom is counted as a center....
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