Journal ArticleDOI
The mechanism of the addition of haloalkanes to alkenes in the presence of dichlorotris(triphenylphosphine)ruthenium(II), [RuCl2(PPh3)3]
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In this paper, the addition of haloalkanes to alkenes in the presence of [RuCl 2 (PPh 3 ) 3 ] has been subjected to a detailed kinetic study.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1985-02-05. It has received 51 citations till now. The article focuses on the topics: Dichlorotris(triphenylphosphine)ruthenium(II) & Alkene.read more
Citations
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Ruthenium-Catalyzed Reactions for Organic Synthesis.
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Non-Metathesis Ruthenium-Catalyzed C−C Bond Formation
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Mechanistic Aspects of the Kharasch Addition Reaction Catalyzed by Organonickel(II) Complexes Containing the Monoanionic Terdentate Aryldiamine Ligand System [C6H2(CH2NMe2)2-2,6-R-4]-†
Lucia A. van de Kuil,David M. Grove,Robert A. Gossage,Jan W. Zwikker,Leonardus W. Jenneskens,and Wiendelt Drenth,Gerard van Koten +6 more
TL;DR: In this paper, a series of para-substituted aryl-nickel catalysts were used for the 1:1 addition of polyhalogenated alkanes to alkenes (Kharasch addition reaction) under mild reaction conditions (25 °C).
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50th Anniversary Perspective: Metal-Catalyzed Living Radical Polymerization: Discovery and Perspective
Makoto Ouchi,Mitsuo Sawamoto +1 more
TL;DR: In this paper, the historical aspects as well as the prospects as a new polymerization tool are described toward advanced structural control or technological materials innovation in various fields, and metal-catalyzed living radical polymerization is used for precise construction of tailor-made polymeric architectures.
References
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New complexes of ruthenium (II) and (III) with triphenylphosphine, triphenylarsine, trichlorostannate, pyridine and other ligands
T.A. Stephenson,G. Wilkinson +1 more
TL;DR: In this article, the interaction of triphenylphosphine, -arsine and -stibine with hydrated ruthenium trichloride in methanol leads to a variety of complexes such as [RuCl2(PPh3)4], [RuCL2(SbPh3]3], RuCl3(Pph3)2CH3OH, [RuC2(CPh3As, Ph3Sb, pyridine etc., with a carbonyl-containing solution] and the corresponding brom
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Solution structure and dynamics of five-coordinate d6 complexes
P. R. Hoffman,K. G. Caulton +1 more
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Radical reactions in the coordination sphere. III. Reactions of dichloro- and trichloroacetic acid esters with 1-olefins catalyzed by dichlorotris(triphenylphosphine)ruthenium(II)
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Radical reactions in the coordination sphere. 4. Addition of carbon tetrachloride to cis-cyclooctene catalyzed by dichlorotris(triphenylphosphine)ruthenium(II)
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Addition of carbon tetrachloride and methyl trichloroacetate to silicon-functional vinylsilanes
TL;DR: In this article, the same authors obtained compounds of type XCCl 2 CH 2 CHClSiY 3 (X = Cl, COOMe; Y = Me, Cl, OEt) by the reactions of carbon tetrachloride and methyl trichloroacetate with vinylchlorosilanes or with vinylethoxysilanes in the presence of dichlorotris(triphenylphosphine)ruthenium(II).
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Radical reactions in the coordination sphere I. Addition of carbon tetrachloride and chloroform to 1-olefins catalyzed by ruthenium(II) complexes.
350. Chlorine activation by redox transfer. Part II. The addition of carbon tetrachloride to olefins
M. Asscher,D. Vofsi +1 more