Book ChapterDOI
The Organometallic and Metal-Organic Chemistry of Molybdenum
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 3 citations till now. The article focuses on the topics: Molybdenum.read more
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Reference EntryDOI
Molybdenum and Molybdenum Compounds
Roger F. Sebenik,A. Richard Burkin,Robert R. Dorfler,John M. Laferty,Gerhard Leichtfried,Hartmut Meyer‐Grünow,Philip C. H. Mitchell,Mark S. Vukasovich,Douglas A. Church,Gary G. Van Riper,James C. Gilliland,Stanley A. Thielke +11 more
TL;DR: In this article, the authors present a survey of the Molybdenum chemistry and its application in various areas of industry, such as mining, automotive, agriculture, and economic aspects.
Journal ArticleDOI
Solvatochromism of Mono- and Dimolybdenum Coordination Compounds of Dipyridyloctatetraene and Linear Solvation Energy Relationship Models Based on the Kamlet-Taft and Drago Scales of Solvent Polarity.
TL;DR: The heteroleptic molybdenum complexes have been analyzed quantitatively by means of linear solvation energy relationships based on Kamlet-Taft solvatochromism parameters, as well as on Drago's "unified scale of solvent polarity".
Journal Article
Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]•O.5CH2Cl2 and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]
TL;DR: In this paper, the reaction between [WBr 3 (CO) 2 (η 5 -C 5 H 5 )] and excess of Tl(SC 6 F 5 ) affords Tl[WBr 2 (CO), η 5 −C 5H 5 )] (2b) as the major product and [W(SC6F 5 ) 3 ( CO), Δ − 5 − C 5 H5 )] (3) as minor product.
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Journal ArticleDOI
Reaktionen von Carbonylmetall‐Anionen mit kationischen Olefinkomplexen: Ethylen‐verbrückte Komplexe von Molybdän, Wolfram und Rhenium
TL;DR: In this article, the structure of 5 was determined by x-ray analysis and the reaction of carbonyl metal anions with Cationic Olefin Complexes: Ethylen Bridged Complexes.
Journal ArticleDOI
Fluxional behaviour in η3-allyl complexes of cr, mo and w as shown by magnetisation transfer difference spectroscopy (MTDS)
TL;DR: In this article, magnetisation transfer difference spectroscopy (MTDS) was used to detect interconversion of the isomers Ia and Ib (IIa and IIb).
Journal ArticleDOI
Pentacarbonylmetallderivatevon phosphinidenen und diphosphenen
TL;DR: In this article, the reaction of Na 2 [M 2 CO 10 ] (M = Cr, Mo, W) with RPCl 2 (R = mesityl, CH(SiMe 3 ) 2 ) yields, depending on the reaction conditions as well as on the steric demand of R, phosphinidene compounds [(CO) 5 M] 2 PR and diphosphene species (n = 1, 2).
Journal ArticleDOI
Molybdenum(II) and tungsten(II) M(CO)(RC2R′)L2X2 alkyne complexes
TL;DR: Mo (CO) (PhC 2 H) (P Et 3 ) 2 Br 2 cristallise dans le systeme monoclinique, groupe d'espace P2 1/n et sa structure est affinee jusqu'a R=0,048 as mentioned in this paper.
Journal ArticleDOI