Book ChapterDOI
The Organometallic and Metal-Organic Chemistry of Molybdenum
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 3 citations till now. The article focuses on the topics: Molybdenum.read more
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Reference EntryDOI
Molybdenum and Molybdenum Compounds
Roger F. Sebenik,A. Richard Burkin,Robert R. Dorfler,John M. Laferty,Gerhard Leichtfried,Hartmut Meyer‐Grünow,Philip C. H. Mitchell,Mark S. Vukasovich,Douglas A. Church,Gary G. Van Riper,James C. Gilliland,Stanley A. Thielke +11 more
TL;DR: In this article, the authors present a survey of the Molybdenum chemistry and its application in various areas of industry, such as mining, automotive, agriculture, and economic aspects.
Journal ArticleDOI
Solvatochromism of Mono- and Dimolybdenum Coordination Compounds of Dipyridyloctatetraene and Linear Solvation Energy Relationship Models Based on the Kamlet-Taft and Drago Scales of Solvent Polarity.
TL;DR: The heteroleptic molybdenum complexes have been analyzed quantitatively by means of linear solvation energy relationships based on Kamlet-Taft solvatochromism parameters, as well as on Drago's "unified scale of solvent polarity".
Journal Article
Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]•O.5CH2Cl2 and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]
TL;DR: In this paper, the reaction between [WBr 3 (CO) 2 (η 5 -C 5 H 5 )] and excess of Tl(SC 6 F 5 ) affords Tl[WBr 2 (CO), η 5 −C 5H 5 )] (2b) as the major product and [W(SC6F 5 ) 3 ( CO), Δ − 5 − C 5 H5 )] (3) as minor product.
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Journal ArticleDOI
Molybdenum carbyne, vinylidene, and ketenyl complexes with hydrotris(3,5-dimethylpyrazolyl)borate ligands
TL;DR: The carbyne compelexes can be deprotonated at low temperature to form anionic vinylidene complexes that are susceptible to electrophilic attack by methyl iodide or ethyl iodide at the β-carbon as discussed by the authors.
Journal ArticleDOI
Synthesis and thermolysis of neutral metal formyl complexes of molybdenum, tungsten, manganese, and rhenium
Journal ArticleDOI
Metal clusters. 26. Hydrogenation of bridging alkyne ligands in dinuclear molybdenum complexes
S. Slater,E. L. Muetterties +1 more
Journal ArticleDOI
The molybdenum-molybdenum triple bond. 11. 1,1- and 1,2-Disubstituted dimolybdenum compounds of formula Mo2X2(CH2SiMe3)4. Observation of rotation about the triple bond Mo.tplbond.Mo
Journal ArticleDOI
Controlling the regioselectivity of nucleophilic addition on unsaturated ligands bound to molybdenum. The cationic [CpMo(NO)(CO)(cyclooctenyl)]+ system
TL;DR: The authors observe une tres haute regioselectivite dans les additions nucleophiles aux 2 isomeres du cation [CpMo(NO)(CO)(cyclooctenyl)] +.