Book ChapterDOI
The Organometallic and Metal-Organic Chemistry of Molybdenum
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 3 citations till now. The article focuses on the topics: Molybdenum.read more
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Reference EntryDOI
Molybdenum and Molybdenum Compounds
Roger F. Sebenik,A. Richard Burkin,Robert R. Dorfler,John M. Laferty,Gerhard Leichtfried,Hartmut Meyer‐Grünow,Philip C. H. Mitchell,Mark S. Vukasovich,Douglas A. Church,Gary G. Van Riper,James C. Gilliland,Stanley A. Thielke +11 more
TL;DR: In this article, the authors present a survey of the Molybdenum chemistry and its application in various areas of industry, such as mining, automotive, agriculture, and economic aspects.
Journal ArticleDOI
Solvatochromism of Mono- and Dimolybdenum Coordination Compounds of Dipyridyloctatetraene and Linear Solvation Energy Relationship Models Based on the Kamlet-Taft and Drago Scales of Solvent Polarity.
TL;DR: The heteroleptic molybdenum complexes have been analyzed quantitatively by means of linear solvation energy relationships based on Kamlet-Taft solvatochromism parameters, as well as on Drago's "unified scale of solvent polarity".
Journal Article
Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]•O.5CH2Cl2 and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]
TL;DR: In this paper, the reaction between [WBr 3 (CO) 2 (η 5 -C 5 H 5 )] and excess of Tl(SC 6 F 5 ) affords Tl[WBr 2 (CO), η 5 −C 5H 5 )] (2b) as the major product and [W(SC6F 5 ) 3 ( CO), Δ − 5 − C 5 H5 )] (3) as minor product.
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Journal ArticleDOI
Oxygen tripod ligand supported molybdenum and tungsten carbyne complexes: carbon-carbon bond formation reactions. Crystal structures of [L(CO)2WCC6H4-p-CH3] and L− = [(C5H5)Co{P(O)(OCH3)2}3]−
TL;DR: Several carbyne complexes of the type [L R (CO) 2 MCC 6 H 4 - p -CH 3 ] (1) have been synthesized as discussed by the authors.
Journal ArticleDOI
Mass Spectroscopic Studies on Ion-Molecule Reactions of CF3+ with Benzene and Toluene at Near-Thermal Energy
TL;DR: In this paper, gas-phase ion-molecule reactions of CF3+ with C6H6 and C6h5CH3 were studied at near-thermal energy by using an ion-beam apparatus.
Journal ArticleDOI
Synthesis and properties of (η5-6,6-dimethylcyclohexadienyl)molybdenum ((dmCh)MoLn) complexes. X-ray structure of [(dmCh)(CO)2Mo]2
TL;DR: In this article, the ancillary character of the 6,6-dimethylcyclohexadienyl ligand (dmCh) was examined via the syntheses of various (DMCh)MoL n derivatives.
Journal ArticleDOI
Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 94. Synthesis of di- and tri-metal compounds via the reagents [M(C–CCBut)(CO)2(η-C5H5)](M = Mo or W)
TL;DR: The alkynylmethylidynemetal compounds react with [Fe2(CO)9] in thf (tetrahydrofuran) at ambient temperatures to afford via alkylidyne group coupling the trimetal complexes in good yield.
Journal ArticleDOI
Dicarbonyl(η5‐cyclopentadienyl)molybdän‐Komplexe mit 2‐Iminocarboxylat als Chelatliganden1)
TL;DR: In this article, a series of chiral 2-iminocarboxylato complexes (η5-C5H5)(CO)2MoN(R2)C(R1)COO (1) (R1 = H, Me, Et, i-Pr; R2 = H and Me, Ph, OH, NH2, NHPh, (S)-CHMePh, CH2CO2Et) wurde aus (