Book ChapterDOI
The Organometallic and Metal-Organic Chemistry of Molybdenum
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 3 citations till now. The article focuses on the topics: Molybdenum.read more
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Reference EntryDOI
Molybdenum and Molybdenum Compounds
Roger F. Sebenik,A. Richard Burkin,Robert R. Dorfler,John M. Laferty,Gerhard Leichtfried,Hartmut Meyer‐Grünow,Philip C. H. Mitchell,Mark S. Vukasovich,Douglas A. Church,Gary G. Van Riper,James C. Gilliland,Stanley A. Thielke +11 more
TL;DR: In this article, the authors present a survey of the Molybdenum chemistry and its application in various areas of industry, such as mining, automotive, agriculture, and economic aspects.
Journal ArticleDOI
Solvatochromism of Mono- and Dimolybdenum Coordination Compounds of Dipyridyloctatetraene and Linear Solvation Energy Relationship Models Based on the Kamlet-Taft and Drago Scales of Solvent Polarity.
TL;DR: The heteroleptic molybdenum complexes have been analyzed quantitatively by means of linear solvation energy relationships based on Kamlet-Taft solvatochromism parameters, as well as on Drago's "unified scale of solvent polarity".
Journal Article
Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]•O.5CH2Cl2 and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]
TL;DR: In this paper, the reaction between [WBr 3 (CO) 2 (η 5 -C 5 H 5 )] and excess of Tl(SC 6 F 5 ) affords Tl[WBr 2 (CO), η 5 −C 5H 5 )] (2b) as the major product and [W(SC6F 5 ) 3 ( CO), Δ − 5 − C 5 H5 )] (3) as minor product.
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Journal ArticleDOI
Molybdenum and tungsten nitrosyl complexes containing bulky alkoxy, aryloxy, and arylamido ligands: their electrochemical behaviour and the structure of [Mo{HB(Me2pz)3}(NO)I(OCH2CH2CH2Br)]
Christopher J. Jones,Jon A. McCleverty,Bryan D. Neaves,Sarah J. Reynolds,Harry Adams,Neil A. Bailey,Gianfranco Denti +6 more
TL;DR: In this paper, the six-coordinate nature of [Mo{HB(Me2pz)3}(NO)I(OCH 2CH2CH2Br)] was confirmed and the Mo-O bond distance was 1.89 A, comparable to that in other related compounds.
Journal ArticleDOI
Synthesis, crystal and molecular structure, and reactions of the bridging vinylidenedicobalt complex (.mu.-CCH2)(CpCoCO)2. Reaction with molybdenum hydrides to give a heteronuclear cluster complex
TL;DR: In this paper, the premier complexe μ-vinylidene (μ−CCH 2 )(CpCoCO) 2 qui est rapidement protone par HBF 4 sur le C−β for donner un sel μ-ethylidyne.
Journal ArticleDOI
The first example of a dinitrosylmolybdenum alkylidene complex: synthesis, spectroscopic characterization and metathesis activity
TL;DR: The first spectrally characterized example of a stable dinitrosylmetal ethylidene complex, [(AlCl 2 ) 2 (μ-O-i-Pr) 2 Mo(NO) 2 (CHMe)], is reported in this article.
Journal ArticleDOI
Addition of dimethylcyanamide to hexakis(alkoxy)dimolybdenum compounds
Journal ArticleDOI
Mono- and bi-metallic complexes based on redox-active tris(3,5-dimethylpyrazolyl)borato-molybdenum nitrosyls, part III. (1) Complexes containing meta-substituted benzene- and naphthalenediols or -diamines
TL;DR: In this paper, the interaction between the redox centres in these new species is intermediate (YC6H4Y-m; NHC10H6NH-1,5) or weak (OC10H 6O).