Book ChapterDOI
The Organometallic and Metal-Organic Chemistry of Molybdenum
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 3 citations till now. The article focuses on the topics: Molybdenum.read more
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Reference EntryDOI
Molybdenum and Molybdenum Compounds
Roger F. Sebenik,A. Richard Burkin,Robert R. Dorfler,John M. Laferty,Gerhard Leichtfried,Hartmut Meyer‐Grünow,Philip C. H. Mitchell,Mark S. Vukasovich,Douglas A. Church,Gary G. Van Riper,James C. Gilliland,Stanley A. Thielke +11 more
TL;DR: In this article, the authors present a survey of the Molybdenum chemistry and its application in various areas of industry, such as mining, automotive, agriculture, and economic aspects.
Journal ArticleDOI
Solvatochromism of Mono- and Dimolybdenum Coordination Compounds of Dipyridyloctatetraene and Linear Solvation Energy Relationship Models Based on the Kamlet-Taft and Drago Scales of Solvent Polarity.
TL;DR: The heteroleptic molybdenum complexes have been analyzed quantitatively by means of linear solvation energy relationships based on Kamlet-Taft solvatochromism parameters, as well as on Drago's "unified scale of solvent polarity".
Journal Article
Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]•O.5CH2Cl2 and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]
TL;DR: In this paper, the reaction between [WBr 3 (CO) 2 (η 5 -C 5 H 5 )] and excess of Tl(SC 6 F 5 ) affords Tl[WBr 2 (CO), η 5 −C 5H 5 )] (2b) as the major product and [W(SC6F 5 ) 3 ( CO), Δ − 5 − C 5 H5 )] (3) as minor product.
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Journal ArticleDOI
Efficient syntheses of new fulvalene-bridged carbonyl complexes of cobalt, ruthenium, chromium, molybdenum, and tungsten
TL;DR: Preparation de (η 5 : η 5 -C 10 H 8 )(CO) 4 Co 2, Co 2 et al. (CO) 6 M 2 (M=Cr, Mo, W) as mentioned in this paper.
Journal ArticleDOI
Metal clusters. 24. Synthesis and structure of heteronuclear metal carbide clusters
Journal ArticleDOI
Reactions of the metal-metal triple bond in Cp2Mo2(CO)4 and related complexes
TL;DR: The reactions of the MM triple bonds in compounds of type Cp 2 M 2 (CO) 4 (M = Cr, Mo or W) are reviewed in this article.
Journal ArticleDOI
Synthesis, structure, and reactivity of zerovalent group 6 metal pentacarbonyl aryl oxide complexes. Reactions with carbon dioxide
TL;DR: In the absence of a carbon monoxide atmosphere these mononuclear species readily aggregate via a CO dissociation pathway to the tetranuclear species [Et 4 N] 4 [M(CO) 3 OR] 4.
Journal ArticleDOI
Controlled ring-opening metathesis polymerization by molybdenum and tungsten alkylidene complexes
TL;DR: In this article, a complex of the type W(CHtBu)(NAr)Cl2(dme) (Ar = 2,6-diisopropylphenyl) with PCl5 in dimethoxyethane is presented.