Book ChapterDOI
The Organometallic and Metal-Organic Chemistry of Molybdenum
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 3 citations till now. The article focuses on the topics: Molybdenum.read more
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Reference EntryDOI
Molybdenum and Molybdenum Compounds
Roger F. Sebenik,A. Richard Burkin,Robert R. Dorfler,John M. Laferty,Gerhard Leichtfried,Hartmut Meyer‐Grünow,Philip C. H. Mitchell,Mark S. Vukasovich,Douglas A. Church,Gary G. Van Riper,James C. Gilliland,Stanley A. Thielke +11 more
TL;DR: In this article, the authors present a survey of the Molybdenum chemistry and its application in various areas of industry, such as mining, automotive, agriculture, and economic aspects.
Journal ArticleDOI
Solvatochromism of Mono- and Dimolybdenum Coordination Compounds of Dipyridyloctatetraene and Linear Solvation Energy Relationship Models Based on the Kamlet-Taft and Drago Scales of Solvent Polarity.
TL;DR: The heteroleptic molybdenum complexes have been analyzed quantitatively by means of linear solvation energy relationships based on Kamlet-Taft solvatochromism parameters, as well as on Drago's "unified scale of solvent polarity".
Journal Article
Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]•O.5CH2Cl2 and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]
TL;DR: In this paper, the reaction between [WBr 3 (CO) 2 (η 5 -C 5 H 5 )] and excess of Tl(SC 6 F 5 ) affords Tl[WBr 2 (CO), η 5 −C 5H 5 )] (2b) as the major product and [W(SC6F 5 ) 3 ( CO), Δ − 5 − C 5 H5 )] (3) as minor product.
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Journal ArticleDOI
The molybdenum-molybdenum triple bond. 8. bis(6-methyl-2-pyridyl)methyltetrakis(dimethylamido)dimolybdenum
Journal ArticleDOI
Synthesis and crystal structures of chloro(trimethylphosphine)tris(trimethylsilylmethyl)molybdenum(IV) and Di-µ-chloro-bis[bis(carbonyl)trimethylphosphine(1—2-η-trimethylsilylmethylcarbonyl)molybdenum(II)]
Ernesto Carmona Guzman,Geoffrey Wilkinson,Robin D. Rogers,William E. Hunter,Michael J. Zaworotko,Jerry L. Atwood +5 more
TL;DR: In this paper, the crystal structures of MoCl(CH2SiMe3)3(PMe3), and [MoCl(COR)(CO)2-(PMe 3)]2 have been determined from three-dimensional X-ray diffraction data collected by counter methods.
Journal ArticleDOI
Interactions of [Mo(Co)6] and [Mo(CO)3(C6H5CH3)] with O2N2– and O2N3-donor macrocycles and the X-ray crystal structure of tetracarbonyl(6,7,16,17-tetrahydro-15H-dibenzo[e,n][1,4,8,12]dioxadiazacyclopentadecine)-molybdenum–toluene (2/1)
TL;DR: In this paper, the crystal and molecular structure of [Mo(CO)4L1]·5C6H5CH3 has been solved by X-ray diffraction methods.
Journal ArticleDOI
Formation and stability of 1,1- and 1,2-bis(dimethylamido)tetrakis(trimethylsiylmethyl)dimolybdenum(MoMo)
TL;DR: In this article, the reaction of hexane solutions of 1,2-Mo2Br2-(CH2SiMe3)4 with LiNMe2 and HNMe 2 gives 1, 1- and 1, 2 -Mo2(NME2)2(CH 2SiMe 3)4, respectively, which, once formed, do not isomerize readily.
Journal ArticleDOI
A study of the protonation and alkylation oft-butyl isocyanide intrans-[M(CNBu-t 2(Ph2PCH2CH2PPh2)2] (M = Mo or W): Formation of carbyne-type complexes and theirtrans- tocis-isomerization
M. Fernanda,N.N. Carvalho,Cristina M. C. Laranjeira,Antónia T. Z. Nobre,Armando J. L. Pombeiro,Ana C. A. M. Viegas,Raymond L. Richards +6 more
TL;DR: In this article, a mixture of aminocarbyne complexestrans pluscis and hydridocompounds was shown to be possible with an alkylating agent.