Book ChapterDOI
The Organometallic and Metal-Organic Chemistry of Molybdenum
Reads0
Chats0
About:
This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 3 citations till now. The article focuses on the topics: Molybdenum.read more
Citations
More filters
Reference EntryDOI
Molybdenum and Molybdenum Compounds
Roger F. Sebenik,A. Richard Burkin,Robert R. Dorfler,John M. Laferty,Gerhard Leichtfried,Hartmut Meyer‐Grünow,Philip C. H. Mitchell,Mark S. Vukasovich,Douglas A. Church,Gary G. Van Riper,James C. Gilliland,Stanley A. Thielke +11 more
TL;DR: In this article, the authors present a survey of the Molybdenum chemistry and its application in various areas of industry, such as mining, automotive, agriculture, and economic aspects.
Journal ArticleDOI
Solvatochromism of Mono- and Dimolybdenum Coordination Compounds of Dipyridyloctatetraene and Linear Solvation Energy Relationship Models Based on the Kamlet-Taft and Drago Scales of Solvent Polarity.
TL;DR: The heteroleptic molybdenum complexes have been analyzed quantitatively by means of linear solvation energy relationships based on Kamlet-Taft solvatochromism parameters, as well as on Drago's "unified scale of solvent polarity".
Journal Article
Synthesis and dynamic nuclear magnetic resonance studies of pentafluorobenzenethiolate complexes of molybdenum and tungsten. The crystal and molecular structures of [W(SC6F5)3(CO)(η5-C5H5)]•O.5CH2Cl2 and [N(PPh3)2][Mo(SC6F5)4(η5-C5H5)]
TL;DR: In this paper, the reaction between [WBr 3 (CO) 2 (η 5 -C 5 H 5 )] and excess of Tl(SC 6 F 5 ) affords Tl[WBr 2 (CO), η 5 −C 5H 5 )] (2b) as the major product and [W(SC6F 5 ) 3 ( CO), Δ − 5 − C 5 H5 )] (3) as minor product.
References
More filters
Journal ArticleDOI
Synthesis of bis(η-pentamethylcyclopentadienyl)dimethylmolybdenum using molybdenum atoms
TL;DR: Co-condensation of hexamethylcyclopentadiene with molybdenum atoms forms bis(η-pentamethyl-cyclopentadienyl)dimethylmoly bdenum via a carbon- carbon bond addition reaction to the metal as mentioned in this paper.
Journal ArticleDOI
Interesting synthetic routes from the reinvestigation of the reaction of the M(CO)6 (M=Cr, Mo and W) species with KOH
TL;DR: Reinvestigation of the reaction of M(CO)6 (M=Cr, Mo or W) with KOH has been found to provide a very convenient route to the K[M2H( CO)10] compounds.
Journal ArticleDOI
The role of α-hydrogen elimination reactions in the formation of η3-cyclopropenyl-and η4-cyclopentadiene-molybdenum complexes
TL;DR: In this article, the reaction of the Grignard reagents RMgX (R = Me or CHCH2) with [MoR(η2-PhC2Ph){P(OMe)3}2( η-C5H5)][BF4] leads to selective attack on molybdenum and formation of the complexes, which undergo thermally promoted α-hydrogen elimination reactions to give η3-cyclopropenyl and η4-cyclopentadiene complexes.
Journal ArticleDOI
A new method of preparation of the anionic decacarbonyls M2(CO)102− (M = Cr, Mo, W) and syntheses and properties of Mg(THF)2[M2(CO)10]
TL;DR: In this article, the anionic decacarbonyIs M 2 (CO) 10 2− were synthesized via reduction reactions of CrCl 3, MoCl 5 and WCl 6 with metallic magnesium or sodium amalgam under carbon monoxide.
Journal ArticleDOI
Synthesis and reactivity of [MCl2(CNBut)3(PMe3)2] (M = Mo or W): preparation of [MCl(CNBut)4(PMe3)2]Cl and [M(SnCl3)(CNBut)3(PMe3)3](SnCl3) derivatives. The crystal structure of [MoCl(CNBut)4(PMe3)2]Cl·2Me2CO
TL;DR: The reaction of the sixteen-electron paramagnetic complex [MCl 2 (PMe 3 ) 4 ](M = Mo or W) with CNBu t gives the eighteenelectron diamagnetic seven-coordinate complex [MoCl 2(CNBu t ) 3 (Pme 3 ) 2 ] (1) or [WCl 2 [CNBU t ] 3 (pMe 3 ] (2) ] (3) as mentioned in this paper, which has a capped trigonal prismatic structure in solid state.