The strength and fracture toughness of 18 Ni (350) maraging steel
01 Nov 1971-Metallurgical and Materials Transactions B-process Metallurgy and Materials Processing Science (Springer Science and Business Media LLC)-Vol. 2, Iss: 11, pp 3011-3020
TL;DR: In this article, the influence of microstructure on the strength and fracture toughness of 18 Ni maraging steel was examined by X-ray and neutron diffraction and by optical and electron microscopy.
Abstract: The influence of microstructure on the strength and fracture toughness of 18 Ni (350) maraging steel was examined. Changes in microstructure were followed by X-ray and neutron diffraction and by optical and electron microscopy. These observations have been correlated with the fracture morphology established by scanning electron microscopy. Air cooling this alloy from the austenitizing temperature results in a dislocated martensite. During the initial stage of age hardening, molybdenum atoms tend to cluster (forming preprecipitates) and the cobalt assumes short range ordered positions. Subsequent aging results in Ni3Mo and σ-FeTi with overaging being associated with the formation of equilibrium reverted austenite and Fe2Mo. The fracture behavior is examined in terms of elementary dislocation precipitate interactions. It is suggested that the development of coplanar slip in the underaged conditions leads to its increased stress corrosion susceptibility and decreased fracture toughness. The optimum aged condition is then associated with cross-slip deformation. The fracture behavior of the overaged condition is a dynamic balance between a brittle matrix and the ductile (crack blunting) reverted austenite.
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TL;DR: The microstructure of 17-4 PH stainless steel at various stages of heat treatment, i.e., after solution heat treatment and tempering at 580 °C, and long-term aging at 400 °C have been studied by APFIM and transmission electron microscopy (TEM) as discussed by the authors.
Abstract: The microstructure of 17-4 PH stainless steel at various stages of heat treatment, i.e., after solution heat treatment, tempering at 580 °C, and long-term aging at 400 °C, have been studied by atom probe field ion microscopy (APFIM) and transmission electron microscopy (TEM). The solution-treated specimen consists largely of martensite with a small fraction of δ-ferrite. No precipitates are present in the martensite phase, while spherical fcc-Cu particles are present in the δ-ferrite. After tempering for 4 hours at 580 °C, coherent Cu particles precipitate in the martensite phase. At this stage, the Cr concentration in the martensite phase is still uniform. After 5000 hours aging at 400 °C, the martensite spinodaly decomposes into Fe-rich α and Cr-enriched α′. In addition, fine particles of the G-phase (structure type D8a, space group Fm\(\bar 3\)m) enriched in Si, Ni, and Mn have been found in intimate contact with the Cu precipitates. Following spinodal decomposition of the martensite phase, G-phase precipitation occurs after long-term aging.
205 citations
TL;DR: In this paper, the evolution of microstructure in a 350 grade commercial maraging steel has been examined, and the formation of austenite of different morphologies identified in detail.
Abstract: Evolution of microstructure in a 350 grade commercial maraging steel has been examined. In the earlier stages of aging, the strengthening phases are formed by the heterogeneous precipitation, and these phases have been identified as intermetallic compounds of the Ni3 (Ti, Mo) and Fe2Mo types. The kinetics of precipitation are studied in terms of the activation energy by carrying out isothermal hardness measurements of aged material. The mechanical properties in the peak-aged and overaged conditions were evaluated and the flow behavior examined. The overaging behavior of the steel has been studied and the formation of austenite of different morphologies identified. The crystallography of the austenite has been examined in detail. From the microstructural examination of peak-aged and deformed samples, it could be inferred that the dislocation-precipitate interaction is by precipitate shearing. Increased work hardening of the material in the overaged condition was suggestive of looping of precipitates by dislocations.
168 citations
TL;DR: In this article, a survey on the effect of microstructure on crack propagation mechanisms and fracture toughness is given, where the influence of inclusions and of the material's matrix are treated separately.
133 citations
25 May 2005-Materials Science and Engineering A-structural Materials Properties Microstructure and Processing
TL;DR: In this article, the sequence of austenite reversion during overageing in 18 Ni (350) maraging steel was examined and its effects on the mechanical properties were evaluated.
Abstract: The sequence of austenite reversion during overageing in 18 Ni (350) maraging steel was examined and its effects on the mechanical properties were evaluated. Austenite with different morphological features were identified at different stages of overageing. The reverted austenite caused decrease in the yield strength (YS) and ultimate tensile strength (UTS) and increase in the tensile ductility. Though the presence of austenite appeared to be beneficial to impact toughness in the initial stages of overageing, severe embrittlement was noticed in samples subjected to prolonged ageing. The observed deterioration in toughness with continued overageing was associated with the coarsening of intermetallic precipitates formed during the early stages of ageing. Electron probe micro analysis (EPMA) carried out on fracture surface identified the embrittling species as precipitates rich in titanium and nickel.
117 citations
01 Jul 1974-Metallurgical and Materials Transactions B-process Metallurgy and Materials Processing Science
TL;DR: In this paper, the influence of microstructure on the strength, fracture toughness and low cycle fatigue behavior of 17-4 PH stainless steel has been examined, and it was shown that fracture toughness increased with increasing strength level and humidity but were not a function of toughness level.
Abstract: The influence of microstructure on the strength, fracture toughness and low cycle fatigue behavior of 17-4 PH stainless steel has been examined. Aging hardening involves initial formation of coherent copper-rich clusters which transform to incoherent fee ∈-copper precipitates upon further aging. The changes in strength level and strain hardening rates observed during aging are consistent with previously suggested models for precipitation hardening based on differing elastic moduli. The fracture toughness and fatigue crack growth rates were shown to be a function of microstructure and environment. At equivalent strength levels overaging resulted in a higher fracture toughness than did underaging. The fatigue crack growth rates increased with increasing strength level and humidity but were not a function of toughness level. Attempts to correlate the fatigue crack growth rates with monotonie tensile properties were unsuccessful. However when final failure obeyed a critical strain criteria, the fracture toughness behavior could be reasonably described and related to preferential void nucleation and growth at δ-ferrite-matrix interfaces.
108 citations
References
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01 Jan 1956
TL;DR: In this article, the authors present a chemical analysis of X-ray diffraction by Xray Spectrometry and phase-diagram Determination of single crystal structures and phase diagrams.
Abstract: 1. Properties of X-rays. 2. Geometry of Crystals. 3. Diffraction I: Directions of Diffracted Beams. 4. Diffraction II: Intensities of Diffracted Beams. 5. Diffraction III: Non-Ideal Samples. 6. Laure Photographs. 7. Powder Photographs. 8. Diffractometer and Spectrometer. 9. Orientation and Quality of Single Crystals. 10. Structure of Polycrystalline Aggregates. 11. Determination of Crystal Structure. 12. Precise Parameter Measurements. 13. Phase-Diagram Determination. 14. Order-Disorder Transformation. 15. Chemical Analysis of X-ray Diffraction. 16. Chemical Analysis by X-ray Spectrometry. 17. Measurements of Residual Stress. 18. Polymers. 19. Small Angle Scatters. 20. Transmission Electron Microscope.
17,428 citations
TL;DR: In this paper, a quantitative estimate of the increase Δτ0 of the critical resolved shear stress for the case of solid solutions containing spherical and coherent precipitates is made, based on the interaction between edge dislocations and the coherency strain fields.
Abstract: A quantitative estimate is made of the increase Δτ0 of the critical resolved shear stress for the case of solid solutions containing spherical and coherent precipitates. The interaction between edge dislocations and the coherency strain fields is believed to be the strengthening mechanism. The calculation is applied to experimental measurements on Al-Zn and CuCo alloys. For small particles (R/b < 20) the dislocations tend to cut through the precipitates, whereas for larger particles the Orowan mechanism becomes predominant.
249 citations
151 citations
01 Jun 1970
TL;DR: In this paper, the heat treatment response of a 350-grade maraging steel, with the nominal composition 18.5 Ni, 12 Co, 4.6 Mo, 1.4 Ti, balance Fe, has been determined in billet and bar form.
Abstract: The heat treatment response of a 350-grade maraging steel, with the nominal composition 18.5 Ni, 12 Co, 4.6 Mo, 1.4 Ti, balance Fe, has been determined in billet and bar form. When aged at temperatures below 900°F, the material was very susceptible to subcritical crack growth, and premature brittle fracture occurred in unnotched tension specimens loaded at a slow strain rate in laboratory air. Fracture mechanics was used to interpret this behavior. The introduction of reverted austenite significantly decreased the strength level but had little effect on fracture toughness. The resistance to brittle fracture of this material is contrasted with that of high-strength steels currently used by the airplane industry.
53 citations