Journal ArticleDOI
The thermodynamic driving force for CH activation at iridium
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TLDR
In this article, the relationship between the intermolecular oxidative addition reaction of carbon-hydrogen bonds in organic molecules to transition metal centres, and the dissociation energies of the CH, MH, and MR bonds that undergo changes during this process is discussed.About:
This article is published in Polyhedron.The article was published on 1988-01-01. It has received 60 citations till now. The article focuses on the topics: Bond energy & Hydrogen bond.read more
Citations
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Activation of c-h bonds by metal complexes
A. E. Shilov,Georgiy B. Shul'pin +1 more
TL;DR: In this article, it was shown that the same alkylhydridoplatinum(IV) complex is the intermediate in the reaction of ethane with platinum(II) σ-complexes.
Journal ArticleDOI
Theoretical studies on reactions of transition-metal complexes.
Shuqiang Niu,Michael B. Hall +1 more
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Complementary Strategies for Directed C(sp3 )-H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer.
TL;DR: This Review discusses the strengths and weaknesses of three main approaches: transition-metal-catalyzed C-H activation, 1,n-hydrogen atom transfer, and transition- Metal-Catalyzed carbene/nitrene transfer, for the directed functionalization of unactivated C(sp3 )-H bonds.
Journal ArticleDOI
Selectivities in Hydrocarbon Activation: Kinetic and Thermodynamic Investigations of Reversible 1,2-RH-Elimination from (silox)2(tBu3SiNH)TiR (silox = tBu3SiO)
TL;DR: In this article, a first-order process for 1,2-RH/D-elimination from 2-R was shown to achieve 24.8 °C in the presence of C2H4, butadiene, HC2H, and HC2tBu.
References
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Book
Principles and applications of organotransition metal chemistry
TL;DR: A perspective survey of organotransition metal complexes according to ligand substitution processes can be found in this paper, with a focus on transition metal complexes with metal carbon-bonded ligands.
Journal ArticleDOI
C-H and H-H Activation in Transition Metal Complexes and on Surfaces.
J Y Saillard,R Hoffman +1 more
TL;DR: In this paper, the breaking of the H-H bond in H2 and a C-H link in CH4 on both discrete transition metal complexes and on Ni and Ti surfaces is studied, and the essential continuity and similarity of the physical and chemical processes in two cases is demonstrated.
Journal ArticleDOI
Aliphatic hydroxylation catalyzed by iron porphyrin complexes
John T. Groves,Thomas E. Nemo +1 more
TL;DR: Hydroxylation et oxydation de cyclohexane, cycloheptane et cis-decaline, selectivite et stereospecificite, and stereos pecificite are described.