Journal ArticleDOI
The total synthesis of reserpine
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This article is published in Tetrahedron.The article was published on 1958-01-01. It has received 228 citations till now. The article focuses on the topics: Reserpine & Total synthesis.read more
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The Diels--Alder reaction in total synthesis.
TL;DR: The Diels-Alder reaction has both enabled and shaped the art and science of total synthesis over the last few decades to an extent which has yet to be eclipsed by any other transformation in the current synthetic repertoire as mentioned in this paper.
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Catalytic enantioselective Diels--Alder reactions: methods, mechanistic fundamentals, pathways, and applications.
TL;DR: Research by this group on the development and understanding of enantioselective versions of the Diels-Alder reactions is described, based on presentations given first at the University of Cologne, Germany, then at the Roger Adams Award Symposium, and later at the Bürgenstock Conference of 2001.
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Macrolactonizations in the Total Synthesis of Natural Products
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General methods for the construction of complex molecules
TL;DR: The synthesis of a complex organic molecule involves a number of distinctly identifiable operations which are not strictly independent of one another as discussed by the authors, such as the choice of the molecule to be synthesized, the development of a synthetic strategy and plan in general outline, the selection of specific individual steps and their ordering, and the experimental execution of the synthesis.
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Die Diels‐Alder‐Reaktion in der Totalsynthese
TL;DR: In den letzten Jahrzehnten hat wohl keine andere Reaktion das Forschungsgebiet der Totalsynthese mehr gepragt als die Diels-Alder-Reaktion, oftmals als entscheidendes Element einer eleganten Kaskadenreaktion zur Herstellung komplexer Molekulstrukturen.
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Reserpin, der sedative Wirkstoff ausRauwolfia serpentina Benth
TL;DR: The sedative principle of Rauwolfia serpentina Benth has been isolated in pure crystalline form and its chemistry and pharmacology has been studied as discussed by the authors, and its properties and properties have been investigated.
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7-norbornenyl and 7-norbornyl cations
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The action of oxalyl chloride on indoles: a new approach to tryptamines
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Die Konstitution des Reserpins. 8. Mitteilung über Rauwolfia-Alkaloide
L. Dorfman,A. Furlenmeier,Charles F. Huebner,R. Lucas,H. B. MacPhillamy,J. M. Mueller,E. Schlittler,Robert Schwyzer,A. F. St. André +8 more
TL;DR: Reserpine, C33H40O9N2, has been isolated from Rauwolfia serpentina Benth as discussed by the authors and is an ester alkaloid yielding reserpic acid, 3,4,5-trimethoxybenzoic acid and methanol on hydrolysis.