Theory and Application of Cyclic Voltammetry for Measurement of Electrode Reaction Kinetics.
About: This article is published in Analytical Chemistry.The article was published on 1965-10-01. It has received 2826 citations till now. The article focuses on the topics: Cyclic voltammetry.
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TL;DR: In this article, the equation of the linear potential sweep voltammogram is derived for any degree of reversibility of the electrochemical reaction for the following methods: surface voltammetry when both the oxidized and the reduced forms are strongly adsorbed, and a Langmuir isotherm is obeyed, thin layer voltamometry, and linear potential sweeping coulometry.
5,920 citations
TL;DR: Graphene has received increasing attention due to its unique physicochemical properties (high surface area, excellent conductivity, high mechanical strength, and ease of functionalization and mass production).
Abstract: Graphene, emerging as a true 2-dimensional material, has received increasing attention due to its unique physicochemical properties (high surface area, excellent conductivity, high mechanical strength, and ease of functionalization and mass production). This article selectively reviews recent advances in graphene-based electrochemical sensors and biosensors. In particular, graphene for direct electrochemistry of enzyme, its electrocatalytic activity toward small biomolecules (hydrogen peroxide, NADH, dopamine, etc.), and graphenebased enzyme biosensors have been summarized in more detail; Graphene-based DNA sensing and environmental analysis have been discussed. Future perspectives in this rapidly developing field are also discussed.
2,866 citations
TL;DR: Proton-coupled electron transfer is an important mechanism for charge transfer in a wide variety of systems including biology- and materials-oriented venues and several are reviewed.
Abstract: ▪ Abstract Proton-coupled electron transfer (PCET) is an important mechanism for charge transfer in a wide variety of systems including biology- and materials-oriented venues. We review several are...
2,182 citations
TL;DR: In this article, the preparation, characterization, and electrochemical properties of reduced graphene sheet films (rGSFs), investigating especially their electrochemical behavior for several redox systems and electrocatalytic properties towards oxygen and some small molecules.
Abstract: This paper describes the preparation, characterization, and electrochemical properties of reduced graphene sheet films (rGSFs), investigating especially their electrochemical behavior for several redox systems and electrocatalytic properties towards oxygen and some small molecules. The reduced graphene sheets (rGSs) are produced in high yield by a soft chemistry route involving graphite oxidation, ultrasonic exfoliation, and chemical reduction. Transmission electron microscopy (TEM), X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy clearly demonstrate that graphene was successfully synthesized and modified at the surface of a glassy carbon electrode. Several redox species, such as Ru(NH3)63+/2+, Fe(CN)63−/4−, Fe3+/2+ and dopamine, are used to probe the electrochemical properties of these graphene films by using the cyclic voltammetry method. The rGSFs demonstrate fast electron-transfer (ET) kinetics and possess excellent electrocatalytic activity toward oxygen reduction and certain biomolecules. In our opinion, this microstructural and electrochemical information can serve as an important benchmark for graphene-based electrode performances.
1,088 citations
TL;DR: This review of “nanoelectrochemistry” involves a necessary arbitrariness of defining what “nano” means, and attention will be biased toward metal nanoparticles having dimensions of only a small number of nanometers, because it is in the 10 nm and lower size range where many significant recent advances have been made.
Abstract: Nanois a big prefix-word. Much of contemporary chemistry focuses on small scale structures, and indeed, molecular science is intrinsically on the nanometer scale. Selecting material for this review of “nanoelectrochemistry” involved a necessary arbitrariness of defining what “nano” means. Here, it refers to a dimensional scale of electrodes and electrochemical events, as opposed to time or volume or mass. Still, most of molecular chemistry fits within the 1-1000 nm range of dimensions, as does a substantial body of charged or conducting substances, e.g., microand nanoparticles, colloids, emulsions, and aerosols. The topology of conducting substances can have nanoscopic dimensions, with mesoporous materials such as areogels and xerogels being contemporary examples. These are important topics, as are nanoparticle applications in bioanalysis, catalysis, and electrocatalysis, and nanomaterials such as fullerenes, carbon nanotubes and networks, semiconductor nanoparticles, and arrays of nanoelectrodes and nanopores. With apologies to those topics, I have chosen to whittle the scenery down to the electrochemistry of nanoparticles, and single nanoelectrodes and nanopores. Within these, attention will be biased toward metal nanoparticles having dimensions of only a small number of nanometers, because it is in the 10 nm and lower size range where many significant recent advances have been made. Similarly, I will focus mainly on single nanoelectrodes and nanopores, as opposed to arrays thereof. The literature cited here is predominantly not over a decade old; a lot has happened, and quickly. I hope the reader will find it an interesting decade. What has promoted the rapid advances in the 1-10 nm range of dimensions? For nanoparticles, progress has been stimulated by synthetic innovations; for single nanoelectrodes and single nanopores, similarly by advances in methods of fabrication. Further, while making something that is really small can be special, it does not push science forward unless one can demonstrate its size and shape and chemical composition. So some substantial attention will be given to developments in fabrication and characterization. Knowing what you have prompts the more interesting and burning questions of how do its properties (of any kind, spectroscopic, electron transfer, etc). depend on its size, on the dimensions of other substances and structures that it interacts with (as in a nanopore), on the particular geometry of the small size, and of course on the extent that the chemist and electrochemist can tailor the composition and/or surface of the small particle/electrode/pore object to further expand its range of properties and usefulness. The authors cited in this report are leaving the first trackssto some extent tentative trackssin the scientific sand in these areas of nanoscience.
1,020 citations
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TL;DR: In this paper, the integral equations obtained from the boundary value problems were solved and extensive data were calculated which permit construction of stationary electrode polarograms from theory, making it possible to develop diagnostic criteria so that unknown systems can be characterized by studying the variation of peak current, half-peak potential, or ratio of anodic to cathodic peak currents as a function of rate of voltage scan.
Abstract: was developed for solving the integral equations obtained from the boundary value problems, and extensive data were calculated which permit construction of stationary electrode polarograms from theory. Correlations of kinetic and experimental parameters made it possible to develop diagnostic criteria so that unknown systems can be characterized by studying the variation of peak current, half-peak potential, or ratio of anodic to cathodic peak currents as a function of rate of voltage scan.
4,542 citations
TL;DR: In this article, the authors collected the parameters of electrode reactions from the literature and tabulated them using a graph-based approach. But they did not consider the effect of voltage on electrode reactions.
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