Thermal behaviour of diphenylammonium perchlorate

Studies on energetic compounds. Part 8 : Thermolysis of salts of HNO3 and HClO4

Abstract: The thermolysis of various substituted ammonium salts of nitric and perchloric acids has been reviewed in the present communication The mechanistic aspects of thermal decomposition of these salts have been discussed critically It has been observed that the proton transfer process do play a major role during thermolysis of these salts The plausible decomposition pathways have also been described

Thermal behaviour of morpholinium perchlorate

Abstract: Morpholine is a base of moderate strength, comparable with that of ammonia, and capable of forming -onium-type salts. Extensive studies [1,2] have been made on the thermal stability of ammonium perchlorate because of its technological use as an oxidant in solid state rocket propellants. The preparation, characterization and thermal behaviour of morpholinium perchlorate are reported in this note. The study was followed by XRD, IR, TG, DTA and mass spectral techniques.

Thermal behaviour of ethylenediammonium perchlorate

Abstract: Perchlorates are powerful oxidizing agents [1] and are used as oxidants in explosives, pyrotechnics and solid state rocket propellants. Extensive studies have been made on the thermal stability of ammonium and related perchlorates due to their technological importance as oxidants [2,3]. This note reports the preparation, characterization and thermal behaviour of ethylenediammonium perchlorate. The study has been followed by XRD, IR, TG, DTA and MS techniques.