Thermal behaviour of morpholinium perchlorate
TL;DR: In this paper, the preparation, characterization and thermal behaviour of morpholinium perchlorate are reported, followed by XRD, IR, TG, DTA and mass spectral techniques.
About: This article is published in Thermochimica Acta.The article was published on 1980-06-01. It has received 10 citations till now. The article focuses on the topics: Perchlorate & Ammonium perchlorate.
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TL;DR: The mass spectral results suggest that guanidinium perchlorate undergoes thermal decomposition into neutral particles which are then vapourized, ionized, and oxidized to give melamine as discussed by the authors.
Abstract: Thermal decomposition of guanidinium perchlorate has been studied by thermogravimetry, differential thermal analysis, mass spectrometry and X-ray diffractometry. The title compound undergoes crystallographic phase transformation at 180°C before melting at 255°C. It decomposes exothermally into gaseous products in the temperature range 275°C–325°C. The mass spectral results suggest that the compound undergoes thermal decomposition into neutral particles which are then vapourized, ionized and oxidized. The fragment cyanamide is found to undergo trimerization to give melamine.
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TL;DR: The infrared spectra of a number of amine hydrohalides have been measured in the lithium fluoride region as mentioned in this paper, where hydrogen bonding and the torsional oscillations of the groups influence these spectra.
Abstract: The infrared spectra of a number of amine hydrohalides have been measured in the lithium fluoride region.Hydrogen bonding and the torsional oscillations of the groups influence these spectra charac...
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51 citations