Thermal decomposition of oxalatocuprates(II)
About: This article is published in Thermochimica Acta.The article was published on 1982-05-01. It has received 1 citations till now. The article focuses on the topics: Thermal decomposition.
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TL;DR: In this paper, a doubly bridged (μ-oxo-μ-hydroxo)dimolybdenum(VI) complex was proposed and a new trioxo species, |MoO3(C2O4)2|4− was identified and characterized.
4 citations
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TL;DR: In this paper, a simple model of the unit cell in a randomly packed bed of identical hard spheres is constructed by introducing spheres tangent to a central one at random positions around it.
Abstract: A NUMERICAL approach using a digital computer has been used to construct a simple model of the unit cell in a randomly packed bed of identical hard spheres. The cell is built up by introducing spheres tangent to a central one at random positions around it. Each added sphere is accepted and its position recorded only if it does not overlap with any of the ones previously accepted. When there is no room for additional spheres, the cluster is complete and the volume of the unit cell is found. This unit is defined as the polyhedron formed by the perpendicular bisectors of the lines connecting the centre of the original sphere with its neighbours. There is some ambiguity in defining a unit cell in a random packing. The prescription used here has the justification that it is correct for the regular lattices with one sphere per unit cell such as the simple cubic, face centred cubic, and hexagonal close-packed arrangements.
72 citations
TL;DR: In this article, the thermal decomposition of K3[Co(C2O4)3]·3H2O in the solid-state, was studied by thermogravimetry, high temperature reflectance spectroscopy, differential thermal analysis, mass spectrometry, gas evolution analysis, and by magnetic techniques.
52 citations
TL;DR: In this article, the thermal decomposition of a number of cobalt (III) amine complexes, several of them containing the carbonate ion in the coordination sphere, and several metal oxalato complexes were studied by the methods of TGA and DTA.
50 citations
31 citations