Thermal decomposition of thallium(I) perchlorate in presence of chromium(III) oxide
TL;DR: In this paper, the thermal decomposition of an intimate mixture of thallium(I) perchlorate and chromium(III) oxide revealed that chromium-III oxide lowers the decomposition temperature of the mixture and is oxidized into hexavalent state.
About: This article is published in Thermochimica Acta.The article was published on 1974-08-01. It has received 3 citations till now. The article focuses on the topics: Thermal decomposition & Perchlorate.
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TL;DR: In this paper, the effects of three corundum structure oxides, α-Al 2 O 3, α-Cr 2O 3, and α-Fe 2 O3, on the thermal decomposition of sodium and potassium peroxodisulfates (persulfates) under non-isothermal static air conditions and using various oxide/persulfate molar ratios, have been thermoanalytically investigated.
9 citations
TL;DR: In this paper, the reaction between potassium iodate and molybdenum(VI) oxide in mixtures of different mole ratios has been investigated employing TG and DTA techniques in static air atmosphere.
Abstract: The reaction between potassium iodate and molybdenum(VI) oxide in mixtures of different mole ratios has been investigated employing TG and DTA techniques in static air atmosphere. The products are characterised by infrared spectroscopy, chemical analysis and X-ray diffraction studies. The studies indicate the formation of mono-, di-, tri- and tetramolybdates of potassium from mixtures with 2∶1, 1∶1, 2∶3 and 1∶2 mole ratios of KlO3∶MoO3. The kinetics of the reaction was followed and the energy of activation values were computed.
3 citations
TL;DR: In this article, the thermal properties of chromium(III) perchlorate have been investigated using X-ray powder diffraction patterns and infrared spectral measurements, followed by TG and DTA techniques.
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TL;DR: In this article, the characteristic frequencies of 52 metals have been studied in the region 700-240 cm−1 and a particle size of 10 μ or smaller was found to give the best representative spectrum.
501 citations
TL;DR: In this article, the influence of the oxides TiO2, V2O5, Co2O3, MnO2 and Tb4O7 on the thermal decomposition of lithium perchlorate trihydrate was surveyed.
8 citations
TL;DR: In this paper, the reaction at 300°C between molten lithium perchlorate and chromium(III) oxide gave lithium dichromate, and a reaction mechanism was proposed.
5 citations