Thermal decomposition of triethylenediammoniumdiperchlorate
About: This article is published in Thermochimica Acta.The article was published on 1983-12-01. It has received 3 citations till now. The article focuses on the topics: Thermogravimetry & Thermal decomposition.
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TL;DR: The thermolysis of various substituted ammonium salts of nitric and perchloric acids has been reviewed and it has been observed that the proton transfer process do play a major role during thermolyses of these salts.
69 citations
TL;DR: Three salts of phenylenediammonium diperchlorate have been prepared and characterized by X-ray crystallography and the kinetics of thermal decomposition was evaluated by model fitting and isoconversional methods using TG data.
Abstract: Three salts of phenylenediammonium diperchlorate have been prepared and characterized by X-ray crystallography. Their thermal decomposition has been studied by thermogravimetry (TG), differential thermal analysis (DTA), and explosion delay (DE) measurements. The kinetics of thermal decomposition was evaluated by model fitting and isoconversional methods using TG data. The oxidation-reduction reactions near the surface of thermolysing perchlorates may be responsible for the decomposition followed by explosion. The possible pathways of thermolysis have also been proposed.
19 citations
TL;DR: In this article, a comparison between the kinetic parameters value and evolved gas types for the same and different materials is presented in tabulated form and discussed, and the values of kinetic parameters and gas product types are presented in Tabulated forms and discussed.
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51 citations
TL;DR: In this paper, the preparation, characterization and thermal behaviour of morpholinium perchlorate are reported, followed by XRD, IR, TG, DTA and mass spectral techniques.
10 citations
TL;DR: In this paper, the preparation, characterization and thermal behavior of ethylenediammonium perchlorate has been described, followed by XRD, IR, TG, DTA and MS techniques.
9 citations
TL;DR: The mass spectral data suggest that the salt undergoes thermal decomposition into neutral particles which are then vapourized and ionized as well as oxidized as mentioned in this paper, and the heat of phase transformation is calculated to be 2.5 kcal/mol.
Abstract: Thermal decomposition of tetraethylammonium perchlorate has been studied by thermogravimetry, differential thermal analysis and mass spectrometry. The title compound undergoes crystallographic transformation at 98°C and explodes at 298°C. The heat of phase transformation is calculated to be 2.5 kcal/mol. The mass spectral data suggest that the salt undergoes thermal decomposition into neutral particles which are then vapourized and ionized as well as oxidized.
6 citations
4 citations