Thermal degradation studies and kinetic modeling of cardoon (Cynara cardunculus) pyrolysis using thermogravimetric analysis (TGA).

doi:10.1016/J.BIORTECH.2011.02.060

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Thermal degradation studies and kinetic modeling of cardoon (Cynara cardunculus) pyrolysis using thermogravimetric analysis (TGA).

Journal Article•DOI•

Thermal degradation studies and kinetic modeling of cardoon (Cynara cardunculus) pyrolysis using thermogravimetric analysis (TGA).

Theodoros Damartzis¹, Despina Vamvuka², Stelios Sfakiotakis², Anastasia Zabaniotou¹•Institutions (2)

Aristotle University of Thessaloniki¹, Technical University of Crete²

01 May 2011-Bioresource Technology (Elsevier)-Vol. 102, Iss: 10, pp 6230-6238

TL;DR: A variance in the activation energy with conversion was observed when the KAS and OFW models were employed, which reveals that the pyrolysis of cardoon progresses through more complex and multi-step kinetics.

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About: This article is published in Bioresource Technology.The article was published on 2011-05-01. It has received 435 citations till now.

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Pyrolysis kinetics and thermal behavior of waste sawdust biomass using thermogravimetric analysis

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Ranjeet Kumar Mishra¹, Kaustubha Mohanty¹•Institutions (1)

Indian Institute of Technology Guwahati¹

01 Mar 2018-Bioresource Technology

TL;DR: Pyrolysis behavior of three waste biomass using thermogravimetric analysis to determine kinetic parameters at five different heating rates confirmed that these biomass have the potential for fuel and energy production.

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491 citations

Cites background or methods from "Thermal degradation studies and kin..."

...…576 kinetic parameters are shown with instance from other studies (Biagini et al., 2008; Ceylan & 577 Kazan, 2015; Ceylan & Topçu, 2014; Chandrasekaran et al., 2017; Damartzis et al., 2011; 578 Heydari et al., 2015; Slopiecka et al., 2012; Yahiaoui et al., 2015) and summarized in Table 579 6....
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...…(Heydari et al., 2015) Cardoon stems 5, 10, 20, 30 229.50 241.50 - - - - (Damartzis et al., 2011) Cardoon leaves 5, 10, 20, 30 350.17 342.07 - - - - (Damartzis et al., 2011) Nannochloropsis oculata 5, 10, 20 - - - 152.20 - - (Ceylan & Kazan, 2015) Tetraselmis sp. 5, 10, 20 - - - 334.00 - - (Ceylan…...
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...It is important to 539 mention that orders of reaction and pre-exponential factor calculated from the iso-540 conversional methods have no physical significance; it is only considered as fitting 541 parameters (Damartzis et al., 2011)....
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...Coats-Redfern method 299 Coats-Redfern model is a model-free method broadly used for calculation of order of 300 reaction and pre-exponential factor (Damartzis et al., 2011)....
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...…& Topçu, 2014) Lignite coal 1, 6, 9, 12, 15, 18 282.00 275.00 283.00 - - - (Heydari et al., 2015) Cardoon stems 5, 10, 20, 30 229.50 241.50 - - - - (Damartzis et al., 2011) Cardoon leaves 5, 10, 20, 30 350.17 342.07 - - - - (Damartzis et al., 2011) Nannochloropsis oculata 5, 10, 20 - - - 152.20 -…...
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Journal Article•DOI•

The effect of the biomass components lignin, cellulose and hemicellulose on TGA and fixed bed pyrolysis

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Luisa Burhenne¹, Jonas Messmer¹, Thomas Aicher¹, Marie-Pierre Laborie²•Institutions (2)

Fraunhofer Society¹, University of Freiburg²

01 May 2013-Journal of Analytical and Applied Pyrolysis

TL;DR: In this article, the authors investigated the devolatilization kinetics during pyrolysis of three biomass types in a thermogravimetric analyzer (TGA) and derived a one-step multi-component model with three independent parallel reactions for hemicellulose, cellulose and lignin.

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437 citations

Journal Article•DOI•

Investigation of thermodynamic parameters in the pyrolysis conversion of biomass and manure to biochars using thermogravimetric analysis.

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Yiliang Xu¹, Baoliang Chen¹•Institutions (1)

Zhejiang University¹

01 Oct 2013-Bioresource Technology

TL;DR: The thermodynamic parameters of the conversion of two companion pair materials, i.e., rice straw vs dairy manure, and rice bran vs chicken manure, to biochars were characterized by thermogravimetric analysis and the distinct decompositions of biomasses and manures were evaluated.

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393 citations

Cites background or methods from "Thermal degradation studies and kin..."

...Non-isothermal thermogravimetric analysis is the most popular and simplest method to study the kinetics and thermodynamics properties of biomass pyrolysis (Damartzis et al., 2011; Sun et al., 2011; Ounas et al., 2011)....
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...The degradation of lignocellulosic biomass is a very complex process, mainly due to the large number and the diverse nature of the occurring reactions (Damartzis et al., 2011)....
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...The three independent parallel (IPR) model was used in this study for its simple form and good predication (Damartzis et al., 2011; Sun et al., 2011)....
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Journal Article•DOI•

Thermogravimetric-mass spectrometric analysis of lignocellulosic and marine biomass pyrolysis.

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Luz Sánchez-Silva¹, D. López-González¹, José Villaseñor¹, Paula Sánchez¹, José Luis Valverde¹ - Show less +1 more•Institutions (1)

University of Castilla–La Mancha¹

01 Apr 2012-Bioresource Technology

TL;DR: The proposed model successfully predicted the pyrolytic behaviour of these samples resulting to be statistically meaningful, and was adopted as a multiple-step model for thermogravimetric analysis coupled with mass spectrometry.

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334 citations

Journal Article•DOI•

Pyrolysis kinetics of hazelnut husk using thermogravimetric analysis.

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Selim Ceylan¹, Yildiray Topcu¹•Institutions (1)

Ondokuz Mayıs University¹

01 Mar 2014-Bioresource Technology

TL;DR: Physicochemical analysis results showed that hazelnut husk has a high calorimetric value and high volatile matter content and it was concluded that this biomass can become useful source of energy or chemicals.

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305 citations

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References

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Open Access

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Journal Article•DOI•

Reaction Kinetics in Differential Thermal Analysis

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H. E. Kissinger

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Journal Article•DOI•

Modeling chemical and physical processes of wood and biomass pyrolysis

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Colomba Di Blasi¹•Institutions (1)

University of Naples Federico II¹

01 Feb 2008-Progress in Energy and Combustion Science

TL;DR: In this article, the state of the art in modeling chemical and physical processes of wood and biomass pyrolysis is reported, and the main achievements of numerical simulations are discussed.

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1,495 citations

"Thermal degradation studies and kin..." refers background in this paper

...The combustible gases, as well as the liquid products, can be used as fuel due to their high calorific value (Di Blasi, 2008a)....
[...]
...…only with the chemical transformation from one phase to another (i.e. solid-to-gas, and solid-to-liquid reactions) (Babu and Chaurasia, 2004; Di Blasi, 2008b; Janse et al., 2000), while others consider biomass as a mixture of its main constituents, namely cellulose, hemicellulose and lignin…...
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Journal Article•DOI•

The determination of activation energy from linear heating rate experiments: a comparison of the accuracy of isoconversion methods

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Marco J. Starink¹•Institutions (1)

University of Southampton¹

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TL;DR: In this article, a classification of model-free isoconversion methods for the calculation of activation energies of thermally activated reactions is proposed, by deriving expressions for the main sources of error which includes the inaccuracy in reaction rate measurement, approximations for the temperature integral and inaccuracies in determination of temperature for equivalent fraction transformed.

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1,393 citations

"Thermal degradation studies and kin..." refers methods in this paper

...By introducing the approximation (Starink, 2003; Sbirrazzuoli et al., 1999 Starink, 2007; Doyle, 1965)....
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Journal Article•DOI•

Series Approximations to the Equation of Thermogravimetric Data

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Charles D. Doyle¹•Institutions (1)

General Electric¹

01 Jul 1965-Nature

TL;DR: In this paper, the authors show which of four abbreviated series approximations most nearly approaches this ideal, and show that the best balance of accuracy and convenience is achieved by the use of series taken to as few terms as possible.

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Abstract: THE equation of the plot of thermogravimetric data is useful in kinetic analysis (1–12), but since it contains an exponential integral, many workers prefer approximate expressions. The best balance of accuracy and convenience is achieved by the use of series taken to as few terms as possible, and it is the purpose of this communication to show which of four such abbreviated series approximations most nearly approaches this ideal.

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504 citations

"Thermal degradation studies and kin..." refers methods in this paper

...By introducing the approximation (Starink, 2003; Sbirrazzuoli et al., 1999 Starink, 2007; Doyle, 1965)....
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...The derivation of this correlation is based on Doyle’s approximation (Doyle, 1965): logðpðxÞÞ 2:315þ 0:457x ð10Þ The final form of the OFW equation is expressed below: log b ¼ log AE RgðaÞ 2:315 0:457 E RT ð11Þ It is evident that a linear plot of log b versus the inverse temperature is sufficient…...
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...The derivation of this correlation is based on Doyle’s approximation (Doyle, 1965):...
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Journal Article•DOI•

Pyrolysis characteristics and kinetics of municipal solid wastes

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Lars Sørum¹, Morten Grønli², Johan E. Hustad¹•Institutions (2)

Norwegian University of Science and Technology¹, SINTEF²

01 Jul 2001-Fuel

TL;DR: In this paper, the pyrolysis characteristics of 11 different components, representing the dry cellulosic fraction and plastics of municipal solid waste (MSW) have been investigated at a constant heating rate of 10°C/min in an inert atmosphere.

...read moreread less

490 citations

"Thermal degradation studies and kin..." refers background or methods in this paper

...The activation energy and pre-exponential factor values are within the ranges that have been reported for lignocellulosic materials (Sørum et al., 2001; Barneto et al., 2010; Vamvuka et al., 2010)....
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...In this work, the pyrolysis process was described by three different kinetic models, namely the independent parallel first-order reactions (IPR) model (Sørum et al., 2001), the iso-conversional Kissinger–Akahira-Sunose (KAS) and Ozawa-Flynn-Wall (OFW) models (Kissinger, 1957; Flynn, 1983)....
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