Thermally induced electron-transfer reactions of heterometallic dinuclear complexes in the solid state
TL;DR: In this article, thermal analysis of dinuclear complexes of the composition [L2MnII(H2O)2] has been carried out and the rate constant of electron transfer has been evaluated from DTA curves at different temperatures.
About: This article is published in Polyhedron.The article was published on 1996-06-01. It has received 7 citations till now. The article focuses on the topics: Electron transfer.
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TL;DR: In this article, three complexes of the formula [Zn(2,2′-biny)(CCl3CO2)2(H2O)]n have been synthesized and characterized by elemental analysis, IR spectra, thermal analysis and single-crystal X-ray diffraction for 1 and 2.
78 citations
TL;DR: In this paper, two new cyano-bridged dinuclear complexes [Cu(dmen)2Fe(CN)5(NO)] (1) and [cu(dmpn)2 Fe(CN), 5(NO), where dmen=2-dimethylaminoethylamine and dmpn=1 dimethylamin-2-propylamine) have been synthesized.
22 citations
TL;DR: In this article, a new alternating double aquo-bridged and single cyano-branched polymeric complex was synthesized and structurally characterized, where the two centrosymmetric [Ba 2 (phen) 4 (H 2 O) 6 ] units are bridged through two trans CN groups of [Fe(CN) 6 ], which results in the formation of a zig-zag polymeric chain.
11 citations
TL;DR: A new cyano-bridged Ca(II)-Fe(III) complex, [Ca2(phen)4(H2O)6Fe(CN)6], was synthesized and structurally characterized in this paper.
8 citations
TL;DR: In this paper, a trimeric cyano-bridged complex (Phen)2(H2O)2CaNC(NC)4FeCNCa(OH2)2]· H2O (1) (where phen=1,10-phenanthroline) has been synthesized and its crystal structure is determined by single crystal X-ray diffraction.
8 citations
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Book•
01 Jan 1978TL;DR: In this article, the normal modes of vibration are illustrated and corresponding vibrational frequencies are listed for each type, including diatomic, triatomic, fouratomic, five-atomic, six-atomic and seven-atomic types.
Abstract: Inorganic molecules (ions) and ligands are classified into diatomic, triatomic, four-atomic, five-atomic, six-atomic, and seven-atomic types, and their normal modes of vibration are illustrated and the corresponding vibrational frequencies are listed for each type. Molecules of other types are grouped into compounds of boron, carbon, silicon, nitrogen, phosphorus, and sulfur, and the structures and infrared (IR)/Raman spectra of select examples are shown for each group. Group frequency charts including band assignments are shown for phosphorus and sulfur compounds. Other group frequency charts include hydrogen stretching frequencies, halogen stretching frequencies, oxygen stretching and bending frequencies, inorganic ions, and metal complexes containing simple coordinating ligands.
Keywords:
inorganic compounds;
coordination compounds;
diatomic molecules (ligands);
triatomic molecules (ligands);
four-atomic molecules (ligands);
five-atomic molecules (ligands);
six-atomic molecules (ligands);
seven-atomic molecules (ligands);
boron compounds;
carbon compounds;
silicon compounds;
nitrogen compounds;
phosphorus compounds;
sulfur compounds;
group frequency charts
15,951 citations
Book•
01 Jan 1999
TL;DR: Cotton and Wilkinson's Advanced Inorganic Chemistry (AIC) as discussed by the authors is one of the most widely used inorganic chemistry books and has been used for more than a quarter century.
Abstract: For more than a quarter century, Cotton and Wilkinson's Advanced Inorganic Chemistry has been the source that students and professional chemists have turned to for the background needed to understand current research literature in inorganic chemistry and aspects of organometallic chemistry. Like its predecessors, this updated Sixth Edition is organized around the periodic table of elements and provides a systematic treatment of the chemistry of all chemical elements and their compounds. It incorporates important recent developments with an emphasis on advances in the interpretation of structure, bonding, and reactivity.From the reviews of the Fifth Edition:* "The first place to go when seeking general information about the chemistry of a particular element, especially when up-to-date, authoritative information is desired." -Journal of the American Chemical Society.* "Every student with a serious interest in inorganic chemistry should have [this book]." -Journal of Chemical Education.* "A mine of information . . . an invaluable guide." -Nature.* "The standard by which all other inorganic chemistry books are judged."-Nouveau Journal de Chimie.* "A masterly overview of the chemistry of the elements."-The Times of London Higher Education Supplement.* "A bonanza of information on important results and developments which could otherwise easily be overlooked in the general deluge of publications." -Angewandte Chemie.
12,231 citations
Book•
01 Oct 1971
TL;DR: The Mössbauer Effect Methodology as mentioned in this paper is a well-known method for nuclear power analysis and it has been used extensively in the nuclear power research community, e.g., in the first Symposium.
Abstract: Mössbauer Effect MethodologyVol. 1. Edited by Irwin J. Gruverman. (Proceedings of the First Symposium, New York City, January 26, 1965.) Pp. viii + 200. (Boston, Mass.: New England Nuclear Corporation, 1965. Distributed by Plenum Press, New York.) $12.50.
1,903 citations
908 citations