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Journal ArticleDOI

Thermochemistry of decomposition of manganese(II) oxalate dihydrate

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TLDR
Differential scanning calorimetry (DSC) has been used to determine the enthalpy of dehydration of manganese(II) oxalate dihydrate as discussed by the authors.
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This article is published in Thermochimica Acta.The article was published on 1977-10-01. It has received 25 citations till now. The article focuses on the topics: Oxalate & Thermal decomposition.

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Kinetic Analysis of Solid-State Reactions: The Universality of Master Plots for Analyzing Isothermal and Nonisothermal Experiments

TL;DR: In this paper, the concept of generalized time, introduced by Ozawa, has been used to define master plots for the analysis of solid-state reactions, regardless of the type of temperature program used for recording the experimental data.
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Kinetic analysis for the removal of a reactive dye from aqueous solution onto hydrotalcite by adsorption.

TL;DR: The removal of a reactive color from aqueous solutions by adsorption onto hydrotalcite particles is investigated using batch rate experiments and it is shown that the sorption capacity is relatively high for most experimental conditions.
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Advantages of Combined Kinetic Analysis of Experimental Data Obtained under Any Heating Profile

TL;DR: In this paper, the combined analysis of experimental data by means of the logarithmic expression of the general differential equation is used for the determination of the kinetic parameters of solid-state reactions.
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A physico-geometric approach to the kinetics of solid-state reactions as exemplified by the thermal dehydration and decomposition of inorganic solids

TL;DR: In this article, the authors reviewed various microscopic studies on the mechanisms of the thermal dehydration and/or decomposition reactions of inorganic solids, the physico-geometric and chemical features of the solid-state reactions were investigated.
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Combined kinetic analysis for crystallization kinetics of non-crystalline solids

TL;DR: In this article, a new method of kinetic analysis that allows the combined analysis of data obtained under different experimental conditions, i.e. heating pathway, is presented for the crystallization of non-crystalline solids.
References
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Differential thermal analysis study of various oxalates in oxygen and nitrogen

TL;DR: Differential thermal analysis (DTA) of 25 oxalates in an atmosphere of oxygen and nitrogen is reported in this paper, showing that in some cases in nitrogen the metal is formed, in other cases the oxide of lowest valency state is produced, while a third group give the same oxide product in nitrogen and oxygen.
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Thermodynamic properties from differential scanning calorimetry by calorimetric methods

TL;DR: In this article, simple theory and techniques are explored and developed to utilize the dif-ferential scanning calorimeter for the determination of heat capacities, glass transition and enthalpies of transition between two thermodynamic states of substances.
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Influence of atmosphere on the thermal decomposition of some transition metal oxalates

TL;DR: The thermal decomposition of manganese, cobalt and nickel oxalate dihydrates in air and nitrogen atmospheres has been studied by TGA and DTA in this paper.
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