Journal ArticleDOI
Thermoelectric power of superionic conductor Ag7I4VO4
K. Hariharan,R. Kaushik +1 more
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In this paper, a superionic conductor with a temperature range from 25 to 60°C was studied and the authors found that the heat of transport is nearly equal to the activation energy of ion migration calculated from the conductivity plots indicating that the material has an average structure.About:
This article is published in Materials Chemistry and Physics.The article was published on 1986-11-01. It has received 3 citations till now. The article focuses on the topics: Seebeck coefficient & Atmospheric temperature range.read more
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Thermoelectric power and electrochemical studies on CdI2–Ag2O–V2O5–B2O3 system
TL;DR: A quaternary super-ion-conducting system, 20CdI2 − 80[xAg2O − y(0.7V2O5 − 0.3B2O3)] where 1 ≤ x/y ≤ 3, has been prepared by melt quenching technique.
Journal ArticleDOI
Influence of glass former to modifier ratio on the transport phenomena of glassy silver iodochromate solid electrolytes
TL;DR: In this article, the influence of glass former to glass modifier ratio on the conduction phenomena has been reported and the possible structural changes occurring in the Ag 2 O-CrO 3 matrix on the variation of the glass former-to modifier ratio have been discussed.
Journal ArticleDOI
Study of xCdI2-(100 − x)(2Ag2O-(0.7V2O5-0.3B2O3)) electrolyte system for application in solid-state primary cells
TL;DR: A glassy solid electrolyte system CdI2-Ag2O-V2O5-B2O3 has been synthesized and the composition with high ionic conductivity is used as an electrolyte in a solid-state cell.
References
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Journal ArticleDOI
Ionic transport in super ionic conductors: a theoretical model
M.J. Rice,W.L. Roth +1 more
TL;DR: In this paper, a theoretical model for ionic transport phenomena in such super ionic conductors is presented based on the hypothesis that there exists in the ionic conductor an energy gap ϵ0 above which ions of mass M, belonging to the conducting species, can be thermally excited from localized ionic states to free-ion like states in which an ion propagates throughout the solid with a velocity vm and energy ϵ m = 1 2 M v m 2.
Journal ArticleDOI
Thermoelectric power of superionic conductors
TL;DR: In this article, a technique for the calculation of the thermoelectric power in many-particle systems exhibiting hopping conduction is presented, which provides very useful information about the microscopic nature of the ion hopping process in solid electrolytes.
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K. Hariharan,Rajiv Kaushik +1 more