Book Chapter•
Trace element characteristics of lavas from destructive plate boundaries
01 Jan 1982-pp 525-548
TL;DR: In this paper, discrimination diagrams are drawn which highlight these various characteristics and therefore enable volcanic arc basalts to he recognized in cases where geological evidence is ambiguous, and the results indicate that the Oman ophiolite complex was made up of back-arc oceanic crust intruded by the products of volcanic arc magmatism.
Abstract: Volcanic are basalts are all characterized by a selective enrichment in incompatible elements of low ionic potential, a feature thought to be due to the input of aqueous fluids from subducted oceanic crust into their mantle source regions. Island arc basalts are additionally characterized by low abundances (for a given degree of fractional crystallization) of incompatible elements of high ionic potential, a feature for which high degrees of melting, stability of minor residual oxide phases, and remelting of depleted mantle are all possible explanations. Calc-alkaline basalts and shoshonites are additionally characterized by enrichment of Th, P, and the light REE in addition to elements of low ionic potential, a feature for which one popular explanation is the contamination of their mantle source regions by a melt derived from subducted sediment.
By careful selection of variables, discrimination diagrams can be drawn which highlight these various characteristics and therefore enable volcanic arc basalts to he recognized in cases where geological evidence is ambiguous. Plots of Y against Cr, K[Yb, Ce/Yb, or Th/Yb against Ta/Yb, and Ce/Sr against Cr are all particularly successful and can be modelled in terms of vectors representing different petrogenctic processes. An additional plot of Ti/Y against Nb/Y is useful for identifying 'anomalous' volcanic arc settings such as Grenada and parts of the Aleutian arc. Intermediate and acid rocks from volcanic are settings can also be recognized using a simple plot of Ti against Zr.
The lavas from the Oman ophiolite complex provide a good test of the application of these techniques. The results indicate that the complex was made up of back-arc oceanic crust intruded by the products of volcanic arc magmatism.
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TL;DR: Two geochemical proxies are particularly important for the identification and classification of oceanic basalts: the Th-Nb proxy for crustal input and hence for demonstrating an oceanic, non-subduction setting; and the Ti-Yb proxy, for melting depth and hence indicating mantle temperature and thickness of the conductive lithosphere as mentioned in this paper.
2,487 citations
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TL;DR: Agarwal et al. as mentioned in this paper presented a comprehensive geochemical data set for the most recent volcanics from the Mariana Islands, which provides new constraints on the timing and nature of fluxes from the subducting slab.
Abstract: We present a comprehensive geochemical data set for the most recent volcanics from the Mariana Islands, which provides new constraints on the timing and nature of fluxes from the subducting slab. The lavas display many features typical of island arc volcanics, with all samples showing large negative niobium anomalies and enrichments in alkaline earth elements and lead (e.g., high Ba/La and Pb/Ce). Importantly, many of these key ratios correlate with a large range in 238U excesses, (238U/230Th) = 0.97–1.56. Geochemical features show island to island variations; lavas from Guguan have the largest 238U-excesses, Pb/Ce and Ba/La ratios, while Agrigan lavas have small 238U excesses, the least radiogenic 143Nd/144Nd, and the largest negative cerium and niobium anomalies. These highly systematic variations enable two discrete slab additions to the subarc mantle to be identified. The geochemical features of the Agrigan lavas are most consistent with a dominant subducted sediment contribution. The added sedimentary component is not identical to bulk subducted sediment and notably shows a marked enrichment of Th relative to Nb. This is most readily explained by melt fractionation of the sediment with residual rutile and transfer of sedimentary material as a melt phase. For most of the highly incompatible elements, the sedimentary contribution dominates the total elemental budgets of the lavas. The characteristics best exemplified by the Guguan lavas are attributed to a slab-derived aqueous fluid phase, and Pb and Sr isotope compositions point toward the subducted, altered oceanic crust as a source of this fluid. Variable addition of the sedimentary component, but near-constant aqueous fluid flux along arc strike, can create the compositional trends observed in the Mariana lavas. High field strength element ratios (Ta/Nb and Zr/Nb) of the sediment poor Guguan lavas are higher than those of most mid-oceanic ridge basalts and suggest a highly depleted subarc mantle prior to any slab additions. The 238U-230Th systematics indicate >350 kyr between sediment and mantle melting but <30 kyr between slab dehydration and eruption of the lavas. This necessitates rapid magma migration rates and suggests that the aqueous fluid itself may trigger major mantle melting.
1,221 citations
Cites background from "Trace element characteristics of la..."
...abundance patterns [Gill, 1981; Kay, 1980; Saunders et al., 1980; Pearce, 1982] that provide key, but complex,...
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TL;DR: In this article, a sequence of eleven adjacent samples (each comprising less than ten microbands) from the Kuruman and Penge Iron-Formations (IFs) in the Late-Archaean to Early-Palaeoproterozoic Transvaal Supergroup display pronounced heavy rare-earth element enrichment, and positive anomalies of LaSN, EuSN, GdSN, YSN, ErSN, but neither positive nor negative CeSN anomalies.
1,170 citations
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TL;DR: Supra-subduction zone ophiolites have the geochemical characteristics of island arcs but the structure of oceanic crust and are thought to have formed by sea-floor spreading directly above subducted oceanic lithosphere.
Abstract: Supra-subduction zone (SSZ) ophiolites have the geochemical characteristics of island arcs but the structure of oceanic crust and are thought to have formed by sea-floor spreading directly above subducted oceanic lithosphere. They differ from ‘MORB’ ophiolites not only in their geochemistry but also in the more depleted nature of their mantle sequences, the more common presence of podiform chromite deposits, and the crystallization of clinopyroxene before plagioclase which is reflected in the high abundance of wehrlite relative to troctolite in their cumulate sequences. Most of the best-preserved ophiolite complexes in orogenic belts are of this type.
Geological reconstructions suggest that most SSZ ophiolites formed during the initial stages of subduction prior to the development of any volcanic arc. Evidence from these ophiolites suggests that the first magma to form in response to intra-oceanic subduction is boninitic in composition, derived by partial melting of hydrated oceanic lithosphere in the ‘mantle wedge’. As subduction proceeds, the magma composition changes to island-arc tholeiite, probably because the hydrated asthenosphere of the ‘mantle wedge’ eventually becomes the dominant mantle source. Other SSZ ophiolites formed in the early stages of back-arc spreading following splitting of a pre-existing arc. Nonetheless the more common mechanism for formation of SSZ ophiolites appears to have been pre-arc rather than back-arc spreading
1,115 citations
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